Chapter 5- The Lipids: Triglycerides, Phospholipids, and Sterols Flashcards
Fats include
triglycerides (fats and oils), phospholipids, and sterols.
Triglycerides are
glycerol backbones and three fatty acids attached.
Fatty acids vary in
carbon chain lengths, degree of unsaturation, and number of double bonds.
Saturation affects the
physical characteristics of the fat and its storage properties.
Trans-fatty acids
which are altered, have the same negative health effects as saturated fatty acids.
Structure of FA
Methyl CH3
Acid COOH
The Length of the Carbon Chain
Long-chain fatty acids are found primarily in meat, fish, and vegetable oils.
Medium- and short-chain fatty acids are found in dairy products.
The Degree of Unsaturation
Saturated fatty acids carry the maximum possible number of hydrogen atoms.
When most of the fatty acids are saturated it is called a saturated fat.
Unsaturated fatty acid
hydrogen atoms and have at least one double bond.
The double bond is considered
the point of unsaturation.
Monounsaturated fatty acids lack
two hydrogen atoms and have one double bond.
When most of the fatty acids are monounsaturated
it is called a monounsaturated fat.
Polyunsaturated fatty acids (PUFA)
lack four or more hydrogen atoms and have at least two or more double bonds.
When most of the fatty acids are polyunsaturated
it is called a polyunsaturated fat.
Linolenic acid is an essential fatty acid.
Omega 3
has the location of the double bond in the third position.
Linoleic acid is an essential fatty acid.
omega-6 fatty acid has the location of the double bond in the sixth position.
Omega Number
refers to the position of the first double bond.
Triglycerides
lipids with three fatty acids attached to a glycerol.
Firmness
Saturated fats are solid at room temperature.
Polyunsaturated fats are liquid at room temperature.
Shorter fatty acid chains are softer at room temperature than longer chains.
Stability
Saturated fat is more resistant to oxidation.
Monounsaturated fat is slightly less susceptible to spoilage.
Polyunsaturated fat spoils most readily.
Protection from rancidity
Sealed in airtight containers away from light
Add antioxidants
Hydrogenation
Hydrogenation
Protects against oxidation therefore prolonging shelf life
Alters texture
Trans-Fatty Acids
Changed from cis to trans configuration and act like saturated fats in the body
Heart disease connection is being researched.
Conjugated linoleic acid is a naturally occurring trans fat that may be beneficial to health.
Phospholipids and sterols
have unique chemical structures that allow them to have unique roles in the body.
Sterols have
multiple-ring structure.
Phospholipids in Foods
Phospholipids contain glycerol, two fatty acids and a phosphate group with a molecule of choline.
Used as emulsifiers in food industry
A well-known phospholipid is lecithin.
Food sources of lecithin include eggs, liver, soybeans, wheat germ and peanuts.
Roles of Phospholipids
Enable transport of lipids across cell membranes
Emulsifiers
Lechithin is made by the liver.
Sterols
A well-known sterol is cholesterol
Sterols in Foods
Found in plant and animal foods
Cholesterol is found in animal foods only—meat, eggs, fish, poultry and dairy products (exogenous).
Roles of Sterols
Starting material for bile acids, sex hormones, adrenal hormones and vitamin D
Structural component of cell membranes
Liver produces 800-1500 mg cholesterol per day (endogenous).
Atherosclerosis is a disease that causes heart attacks. It occurs when cholesterol forms deposits in the artery wall.
Lipids tend to separate from the watery fluids of digestion.
This is due to the hydrophobic nature of lipids.
Digestive enzymes are
hydrophilic, or water loving.
Bile from the liver
emulsifies lipids.
Enzymes
then able to break down lipids to monoglycerides and fatty acids.
Lipid Digestion
In the mouth, the salivary glands release lingual lipase.
Muscle contractions in the stomach disperse fat into smaller droplets. Fat is exposed to gastric lipase enzyme.
In the Small Intestine
Bile is released.
Pancreatic and intestinal enzymes hydrolyze lipids to monoglycerides and fatty acids.
Phospholipids are hydrolyzed.
Sterols are absorbed as is.
unlimited amounts of fat
Can be stored by body in excess
The liver can also convert excess carbohydrate and protein
to fat
Fat needs what to breakdown?
Carbs
Roles of Triglycerides
Energy reserve when stored
Use carbohydrate and protein efficiently
Insulation
Shock protection
Linoleic Acid and the Omega-6 Family
Supplied by vegetable oils and meats
Linolenic Acid and the Omega-3 Family
Must be supplied by food
Important for eyes, brain and heart
Essential FA
cannot be made by the body.
Linoleic Acid and the Omega-6 Family
Linolenic Acid and the Omega-3 Family
High intakes of saturated fat and trans fat and high blood LDL cholesterol
related to increased risk for heart disease.
Omega-3 fatty acids in the diet
appear to have a protective effect.