Chapter 5 Electrons and bonding Flashcards

1
Q

Shells

A

Energy levels

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2
Q

Quantic number, n

A

The energy level number

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3
Q

What are shells made up of

A

Atomic orbitals

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4
Q

Atomic orbitals

A

A region around the nucleus that can hold up to 2 electrons, with opposite spins

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5
Q

Types of atomic orbitals

A
  • s-
  • p-
  • d-
  • f-
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6
Q

s-orbital

A

electron cloud is in the shape of a sphere

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7
Q

p-orbital

A
  • electron cloud is in the shape of a dumbbell
  • there are 3 p-orbitals, at right angles to eachother
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8
Q

d-orbitals

A
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9
Q

Sub-shells

A

Orbitals of the same type are grouped together as these

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10
Q

Ionic bonding

A

Electrostatic attraction between oppositely charged ions

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11
Q

Structure of ionic compounds

A

Giant ionic lattice
Regular arrangement of alternate pattern of positive and negative ions

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12
Q

Properties of ionic compounds

A
  • High melting and boiling points -> lots of energy needed to overcome strong electrostatic attraction between the ions
  • as the charge increases, m.p. and b.p. increase
  • Soluble in polar solvents - breaks down the lattice and water molecules attract + surround each ion
  • Electrical conductivity - do not conduct in solid state because the ions are not mobile
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13
Q

Covalent bonding

A

Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms

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14
Q

When does covalent bonding occur

A
  • Non-metallic elements
  • Compounds of non-metallic elements
  • Polyatomic ions
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15
Q

What is a covalent bond made up of

A

Overlap of atomic orbitals, each containing 1 electron -> gives a shared pair of electrons

The shared pair of electrons is attracted to the nuclei of both the bonding atoms

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16
Q

How does ionic bonding act

A

In all directions

17
Q

How does covalent bonding act

A

Localised - acts only between the shared pair of electrons and the nuclei of the bonding atoms

18
Q

Unusual covalent bonding

A

Boron -> only has 3 outer shell electrons so can only produce 3 covalent bonds = 6 electrons in outer shell

19
Q

Expansion of the octet

A

When sulfur pairs all 6 of its outer shell electrons = 12 outer shell electrons

20
Q

Multiple covalent bond

A

Exit when 2 atoms share more than 1 pair of electrons

21
Q

Dative covalent bond/coordinate bond

A

A covalent bond in which the shared pair of electrons has been supplied by one of the bonding atoms only

22
Q

Examples of dative covalent bonds

A

NH4+

23
Q

How is a dative covalent bond shown?

A

Arrow from the bonding atoms whose electrons they are

24
Q

Average bond enthalpy

A

A measurement of covalent bond strength

The larger the average bond enthalpy, the stronger the covalent bond