Chapter 5- alcohol Flashcards

1
Q

Ortho vs meta vs para

A

O: adjacent
M: in between
P: 180 apart

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2
Q

H bonding

A

Increase BP, MP, solubility

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3
Q

Redox

A
  • PCC: primary to aldehyde vs secondary to ketone

- Jones oxidation: CrO3 in H2SO4

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4
Q

Mesylate

A

SOCH3 as a better leaving group

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5
Q

Tosylate

A

So3C6H4CH3

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6
Q

Protecting group

A

Acetal (primary C with 2OR) or ketal (secondary C with 2 OR) to protect against reactions

  • can revert back to aldehydes and ketones
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7
Q

Quinones

A

Oxidized form of phenol

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