Chapter 5- alcohol Flashcards
1
Q
Ortho vs meta vs para
A
O: adjacent
M: in between
P: 180 apart
2
Q
H bonding
A
Increase BP, MP, solubility
3
Q
Redox
A
- PCC: primary to aldehyde vs secondary to ketone
- Jones oxidation: CrO3 in H2SO4
4
Q
Mesylate
A
SOCH3 as a better leaving group
5
Q
Tosylate
A
So3C6H4CH3
6
Q
Protecting group
A
Acetal (primary C with 2OR) or ketal (secondary C with 2 OR) to protect against reactions
- can revert back to aldehydes and ketones
7
Q
Quinones
A
Oxidized form of phenol