chapter 4c Flashcards
more H+ ions
pH low (acidic)
more OH+ ions
pH high (alkalinity)
negative logarithm of the total hydrogen ion concentration in the solution
pH
acidity or alkalinity, due to relative concentration of H+ and OH ions
pH
humid
arid
inorganic
5 to 7
7 to 9
4 to 10
relationship between pH and %BS
linear relationship
as pH increases
H+ decreases
method by pH meter, more accurate
electrometric method
organic dyes, litmus paper (ex: cornell pH)
colorimetric method
soil test kit
nitrogen, phosphorus, and potassium. next is lime requirement
effects of soil pH on microbial act
fungi: unaffected
bacteria & actinomycetes: inhibited at pH 5
(1) origin of soil acidity
release of hydrogen atoms under natural chemical processes in the soil
rel of H under natural chem
*atmospheric carbon dioxide reacts w/ water to form carbonic acid
*organic molecules reacts w/ water and causes acid dissociation
*oxidation of ammonium nitrogen, sulfur, and iron
(2) origins of soil acidity
accumulation of OM and subsequent release of products of decomposition: fulvic and humic acid
(3) origins of soil acidity
reaction of aluminum cations with water, “hydrolysis”
(4) origins of soil acidity
natural deposition
- lightning deposits nitric acid
- volcanic activity deposits sulfuric acid
- mineral weathering: Pyrite or Fool’s Gold (FeS2) once oxidized, results to formation of acid sulfate soils
(5) origins of soil acidity
human factors
- oxidation of applied synthetic ammonium-based fertilizer
-oxidation of nitrogen compounds in applied animal manure or sewage
- deposition of acid rain (nitric and sulfuric caused by industrialization)
forms of soil acidity
active acidity: due to H+ in soil solution, determined as pH
reserve acidity: due to H+ and Al+++ in the solid phase
ability of soil to resist sudden/drastic changes in pH
buffering capacity
measure of the buffering capacity of soil
reserve and active acidity
buffering capacity is high if
CEC is high
clay content is high
OM content is high
production constraints associated with acid soils
aluminum toxicity- usually damages the root system first
mn toxicity- less common than Al toxicity
nutrient deficiency- P, Ca, and Mo deficiency (also nitrogen)
(4-5) production constraints with acid soils
restricted microbial activities: mineralization of organic N, biological fixation of N
incidence of plant diseases: some plants are more likely to be affected by damping off (fungal disease) and root rot in acid soils
(1) management strategy
reduce acidification
- minimize use of acidifying fertilizer
- reduce leaching of N by use of split applications of fertilizer
- return plant material to soil
(2) management strategy
used acid-tolerant crops
- sweet potato, coffee, radish, tomato, pineapple, strawberry, irish potato
(3-4) management strategy
apply more nutrients
apply agricultural lime
only means of correcting soil acidity
lime
any oxide, hydroxide, or carbonate of Ca or Mg used to neutralize soil acidity
lime
carbonate form
CaCo3 (calcitic limestone)
CaMg(Co3)2 dolomitic limestone
oxide and hydroxide form
CaO (burned lime)
Ca(OH)2 hydrated lime
depends on soil
pH: lower- more lime
exchangeable Al- more, more lime
texture- clayey, more lime
OM- depeds
amount of lime depends on soil
pH: lower- more lime
exchangeable Al- more, more lime
texture- clayey, more lime
OM- depends
amount of lime depends on (2)
type and variety of crops to be grown
amount of lime depends on (3)
kind of lime
- fineness
- chemical guarantee
amount of lime depends on (4)
economic return from lime application
amount of salt that have accumulated in the soil
salinity
expressions of chemical guarantee of lime
oxide content in %CaO r %MgO
calcium oxide equivalent- strength in pure CaO
calcium carbonate equivalent (neutralizing power)- CaCo3
high osmotic potential
low salt concentration
low osmotic potential
high salt concentration
excess Na causes
disperse and swell, affect drainage, aeration, and root penetration. toxicity to plants
ability of substance to conduct electric current
electrical conductivity
ability of an electrolytic solution to conduct electric current
electrical conductivity
index of total ionic concentration in solution
electrical conductivity
more saline
higher EC
correct salinity
irrigation water
correct sodicity
gypsum or sulfur