Chapter 4- Compounds And Stoichiometry Flashcards
Molecular Mass vs Molecular Weight
Molecular weight is the mass of the constituent atoms in a compound as indicated by the molecular formula.
Molar mass is the mass of one mole (6.022×10 to the 23 particles) of a compound. Usually measured in grams per mole.
Gram equivalent weight
The measure of the mass of a substance that can donate one equivalent of the species of interest.
Normality
The ratio of equivalence per liter. Related to molarity by multiplying molarity by the number of equivalence present per mole of compound.
Normality = equivalents/L
Molarity
Morlarity = Normality/n
Equivalents
Moles of the species of interest.
Equivalents are most often seen in acid/base chemistry and oxidation reduction reactions.
Law of constant composition
Any pure sample of a compound will contain the same elements in the same mass ratio.
For example a sample of water will contain two hydrogen atoms per one oxygen atom, in terms of mass for everyone gram of hydrogen, there will be 8g of oxygen.
Empirical vs Molecular formula
Empirical formula is the smallest WHOLE NUMBER RATIO of the elements in a compound.
Molecular formula is either the same or a multiple of the empirical formula gives EXACT NUMBER of atoms of each element in a compound.
How to calculate percent composition
Determine the mass of the individual element and divide by the molar mass of the compound.
Mass of individual element/Molar mass of compound
Combination vs Decomposition
Combination reaction two or more reactants combine to form one product.
Decomposition reactions when reactive chemically broken down into two or more products.
Combustion reaction
When an oxidant (typically oxygen) reacts forming the products water and carbon dioxide
Displacement reaction
When one or more atoms or ions of one compound are replaced with one or more atoms or ions of another compound.
Include single displacement- occurs when one ion of a compound is replaced with another element
double displacement-Occurs when elements from two different compounds trade places with each other to form two new compounds
Neutralization reactions
Where an acid reacts with a base to form a salt usually water
Three rules for balancing equations
- Balancing the least common atoms
- Balancing the more common atoms (usually hydrogen and oxygen)
- Balancing charge if necessary
Limiting reagent
The reactant that will be consumed first in a chemical reaction.
Can be determined by using the balanced equation.
Theoretical vs actual vs percent yield
Theoretical yield is the amount of product generated if all the limiting reactants are consumed with no side reactions.
Actual yield is typically lower than theoretical yield.
Percent yield is calculated by dividing actual yield by theoretical yield and converting to a percentage.
(Actual yield/Theoretical yield) x100