Chapter 4 Flashcards
ionic bond
- between non-metal and metal
- occurs through process of ionization
- electrostatic forces between ions
- between oppositely charged atoms
- electrically neutral
ionization
when electrons are transferred between atoms
electrically neutral
- describe ionic bond
- no net gain or loss of electrons
polyatomic ions
ions with more than one atom
ionic lattice structure
- 3 dimensional structure
- occurs when electrostatic forces between ions in a compound cause them to surround themselves with ions of opposite charge
coordination number
the number of ions surrounding a given ion in an ionic lattice
Describe the melting and boiling points, and volatility of ionic lattice
- high melting and boiling point- a lot of energy needed to break strong electrostatic bonds
- low volatility- tendency to vaporize
What is the state of an ionic lattice in room temperature?
solid
What does it mean when molecules are hydrated?
- when ions from the lattice are surrounded by water molecules
What does it mean when ions are solvated?
- when ions from lattice are surrounded by liquid other than water
- ex oil
Describe electrical conductivity of ionic lattice.
- when solid, can’t conduct electricity
- when aqueous or molten- can conduct
- ions able to move and carry a charge
Describe brittleness of ionic lattice.
- brittle- crystal structure usually shatters when force is applied
What is a binary ionic compound?
Compound with only 2 elements
What areas of the periodic table have the highest tendency to form ionic compounds?
- metals on bottom left and non-metals on top right
- they are most reactive
What values determine if a bond is ionic?
- difference in electronegativity values
- a difference of 1.8 units or more= ionic
How is the covalent bond between two atoms kept at a fixed distance?
The attraction between the nuclei and the shared electrons is balanced by the repulsion between the two nuclei.
What is a covalent bond?
An electrostatic attraction between a pair or electrons and 2 positively charged nuclei
What does the covalent bond release when it is formed?
energy
What are the 2 types of electron pairs in a covalent bond?
bonding pair- bonded
lone pair- non-bonding pair
What is a polar bond?
When there is a difference in electron distribution because of the difference in electronegativity.
What are the effects of a polar bond?
The atom is dipole- with a difference in electric charge.
What are the trends of electronegativity?
Increases along a period
Increases up a group
What bonds are truly non-polar?
Only pure covalent bonds between the same atoms.
What is a coordinate bond?
When one atom donates a pair of electrons to the other atom and the other atom accepts it
What is VSEPR theory?
- valence shell electron pair repulsion theory
- because electron pairs in the same valence shell carry the same charge, they repel each other and spread themselves as far apart as possible