Chapter 4 Flashcards
solutions
homogeneous mixtures of 2+ substances
solvents
present in greatest abundance
solutes
present in lesser abundance
aqueous solution
w/ water
solvation
surrounding of solute by solvent (water); molecular and ionic
dissociation
ionic compounds dissolve by separation into ions
electrolyte
dissociates into ions in aqueous solution; ionic, conducts electricity
nonelectrolyte
doesn’t dissociate (doesn’t form ions); molecular, doesn’t conduct electricity
strong electrolyte
dissociates completely when dissolved
- water-soluble ionic compounds
all ionic compounds =
strong electrolytes
weak electrolytes
only dissociate partially when dissolved
- chemical equilibrium; reaction goes forwards and backwards
precipitation reactions
2 solutions w/ soluble salts –> insoluble salt (precipitate)
precipitate
insoluble solid formed by 2 soluble salts
solubility
amount of substance can be dissolved in solvent
metathesis reactions (exchange)
partner switching
steps to metathesis reactions
- determine ions present
- write formulas for product, cation from 1 reaction w/ anion from other reaction
- check solubility; if insoluble, precipitate forms
molecular equation
lists reactants and products w/o ionic values
complete ionic equation
all strong electrolytes dissociated into ions
- breaks down aqueous species
net ionic equations
doesn’t include spectator ions (cancel out what’s on both sides)
acids
substances that ionize in aqueous solutions to form H+ ions (protons)
- proton donors
monocratic acids
donate 1 H+ per molecule
diprotic acid
donates 2 H+ per molecule
bases
increase amount of OH- ions or accepts H+ ions
strong acids
Hydrochloric acid, HCl
hydrobromic acid, HBr
Hydroiodic acid, HI
Chloric acid, HClO3
perchloric acid, HClO4
nitric acid, HNO3
sulfuric acid, H2SO4
strong bases
Group 1A metal hydroxides (LiOH, NaOH, KOH, RbOH, CsOH
heavy group 2A metal hydroxides (Ca(OH)2, Sr(OH)2, Ba(OH)2)
strong acids and bases
completely dissociate in aq (completely ionized)
weak acids and bases
don’t completely dissociate (partially ionized)
identifying strong/weak electrolytes
- ionic or molecular? –> ionic = strong
- molecular = acid or base?
- if starts w/ H or ends w/ COOH = acid
neutralization reaction
reaction b/w acid and base
neutralization reaction w/ metal hydroxide (base)
product = water + salt
neutralization reaction w/ gas
carbonate/bicarbonate react w/ acid –> water + salt + CO2
oxidation
loss of electrons
reduction
gain of electrons
oxidation number
assigned; determines if redox reaction occured
oxidation number: pure element
0
oxidation number: monatomic ion
same as charge
oxidation number: nonmetals
usually (-)
oxidation number: sum of oxidation numbers
neutral = 0
polyatomic ion = charge of ion(s)
displacement reactions
ion oxidize an element
- reaction b/w metal + acid/metal salt (partner switching)
becoming more (+)
loss of electrons
becoming more (-)
gain electrons
activity series
list of metals in order of decreasing oxidation
- elements higher = more reactive = more easily oxidized
active metals
metals at top of series = most easily oxidized
noble metals
metals at bottom of series = low reactivity
reducing agent
loses electrons (more +), is oxidized
oxidizing agent
gains electrons (more -), is reduced
concentration
amount of solute dissolved in solvent
molarity (M)
concentration of solution
M = (moles of solute)/(volume of solution (L))
dilution
adding solvent to solution; lowers concentration, moles stay the same
- molarity(initial) x volume(initial) = molarity(final) x volume(final)
titration: to calculate concentration of solute in solution
- m1v1 = m2v2
- mL1=? M1=, M2=, ML2=
standard solution
reagent solution of known concentration
equivalence point
point of which equivalent quantities are brought together