Chapter 3 - Crystal Structures Flashcards
Crystal
Solid composed of atoms, ions, or molecules arranged in a pattern that is repeated in three dimensions
Amorphous Solid
Solid lacking in long-range atomic order
Unit Cell
Repeating unit in crystal
Lattice
An infinite 3D array of points having identical surroundings
Crystal Systems
7 Unique Unit cell systems that can be stacked together 3-Dimensionally
Bravais Lattice
14 possible arrangements of atoms in space
FCC
Atoms Per Cell: 4 6 x (1/2) = 3 8 x (1/8) = 1 CN: 12 APF: .74 LC: 2R√2 EX: Cu, Al, Ag, Au, Pt
BCC
Atoms Per Cell: 2 8 x (1/8) = 1 1 x ( 1 ) = 1 CN: 8 APF: .68 LC: 4R/√3 EX:
HCP
Atoms Per Cell: 6 3 x 1 = 3
2 x (1/2) = 1
12 x (1/6)=2
CN: 12
APF: .74
LC:
EX: Cd, Mg, Zn, Zr
Coordination Number
Number of closest Molecules
Atomic Packing Factor
Volume of atoms in Unit Cell
Divided by
Total Volume of Unit Cell
Lattice Constant
Distance between atoms in a unit cell
Miller indices are surrounded by _______ for directions
Square Brackets
ex: [1 1 1]
Miller indices are surrounded by _______ for planes
Parenthesis
ex: (1 1 1)
Miller indices are surrounded by _______ for indicies families
Angle Brackets
ex: