Chapter 3: Biological Macromolecules Flashcards
What are the four major macromolecules?
Carbohydrates, lipids, proteins and nucleic acids
dehydration synthesis
when monomers combine to create polymers and release water as a byproduct
How is water created in a dehydration synthesis reaction?
The hydrogen of one monomer combines with a hydroxyl group of another monomer
How are monomers bonded in a dehydration synthesis reaction?
When a hydrogen and a hydroxyl group form water, the leftover oxygen creates a covalent bond between the monomers
hydrolysis
when a polymer is broken up into its monomer components
What molecule is needed in a hydrolysis reaction?
Water
How are polymers broken into monomers in hydrolysis?
Each monomer gains hydrogen or a hydroxyl group when water is split
What is the stoichiometric formula for carbohydrates?
(CH2O)n
What does ‘n’ represent in the carbohydrate stoichiometric formula?
The number of carbon atoms in the molecule
What is the ratio of carbon to hydrogen to oxygen in carbohydrates?
1:2:1
What are the three subtypes of carbohydrates?
Monosaccharides, disaccharides and polysaccharides
monosaccharides
simple sugars
What is the suffix for most monosaccharides?
-ose
aldehyde group
functional group where carbonyl group is attached to one hydrogen and another group
aldose
monosaccharide with an aldehyde group
ketone group
functional group where carbonyl group is attached to two carbon groups
ketose
monosaccharide with a ketone group
carbonyl group
a carbon and oxygen atom bound by a double bond
What are the three types of monosaccharides by number of carbon atoms?
Trioses, pentoses and hexoses
asymmetric carbon
carbon that is attached to four other atoms or groups
anomeric carbon
the carbon atom in a carbon ring derived from the carbonyl group
α glucose
glucose where the hydroxyl group is below the anomeric carbon
β glucose
glucose where the hydroxyl group is above the anomeric carbon
How many carbons are in a glucose ring?
Six
How many carbons are in a ribose ring?
Five
How many carbons are in a fructose ring?
Five
How many carbons can a carbon ring have and still be stable?
Five or six
What are two common isomers of glucose?
Galactose and fructose
What is another name for an anomeric carbon?
Carbon 1
disaccharide
two monosaccharides bound together
glycosidic bond
a covalent bond that joins a carbohydrate with another molecule
What bond holds together a disaccharide?
A glycosidic bond
What are the two types of glycosidic bonds when glucose is part of a disaccharide?
An alpha bond and a beta bond
alpha glycosidic bond
glycosidic bond that forms below carbon 1 because the OH group was below carbon 1
beta glycosidic bond
glycosidic bond that forms above carbon 1 because the OH group was above carbon 1
What are three common disaccharides?
Lactose, maltose and sucrose
lactose
disaccharide of glucose and galactose
maltose
disaccharide of two glucose molecules
sucrose
disaccharide of glucose and fructose
amylose
a linear-shaped glucose polymer that is a component of starch
amylopectin
a branched glucose polymer that is a component of starch
What bonds join glucose in starch?
Alpha 1-4 glycosidic bonds and alpha 1-6 glycosidic bonds
alpha 1-4 glycosidic bond
glycosidic bond where the carbon 1 of one monomer is joined to the carbon 4 of another monomer
alpha 1-6 glycosidic bond
glycosidic bond where the carbon 1 of one monomer is joined to the carbon 6 of another monomer
Where are alpha 1-4 glycosidic bonds found in starch?
At linearly joined glucoses
Where are alpha 1-6 glycosidic bonds found in starch?
At the branch points between glucoses
What glycosidic bonds are found in amylose?
Alpha 1-4 glycosidic bonds
What glycosidic bonds are found in amylopectin?
Alpha 1-4 and alpha 1-6 glycosidic bonds
What is the animal equivalent of starch?
Glycogen
glycogen
glucose polymer
What is the general structure of glycogen?
It is highly branched
What is the role of glycogen?
To store energy
cellulose
glucose polymer
What is the role of cellulose?
It makes up most of the cell wall in a plant
What is the most abundant natural polymer?
Cellulose
Which bond joins glucose together in cellulose?
Beta 1-4 glycosidic bonds
How is each glucose arranged in cellulose?
They are alternately flipped
chitin
polysaccharide containing nitrogen
What is the main role of chitin?
As an exoskeleton for arthropods and it is part of the cell wall in fungi
What are the two main parts of a fat molecule?
Glycerol and fatty acids
What is glycerol made up of?
Three carbons, five hydrogens and three hydroxyl groups
How many carbons does a fatty acid have?
Four to thirty-six
What bond joins fatty acids to glycerol?
An ester bond through an oxygen
Where are fatty acids joined to glycerol?
Fatty acids are joined to carbon atoms on the glycerol
Through which process are fatty acids joined to glycerols?
Dehydration synthesis reaction
What are other names for fat?
Triacylglycerols or triglycerides