chapter 3 Flashcards

1
Q

how are elements in the periodic table arranged?

A

in order of increasing atomic number

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2
Q

what is metallic structure

A

a lattice of positive ions in a sea of delocalised electrons

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3
Q

what happens to ionisation energy down a group

A

ionisation energy decreases

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4
Q

properties of metallic elements

A

large atomic radii, low ionisation energy, less exothermic electron affinity and low electronegativity

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5
Q

what are electrons in the outer shell known as?

A

valence electrons

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6
Q

how is the periodic table divided

A

in to blocks (s,p,d,f,g)

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7
Q

what is atomic radius?

A

used to describe the size of an atom

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8
Q

what happens to atomic radius down a group?

A

it increases

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9
Q

what happens to atomic radius across a period?

A

decreases

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10
Q

what is ionic radius?

A

a measure of the size of an ion

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11
Q

what happens to ionisation energy down a group?

A

decreases

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12
Q

why does ionisation energy decrease down a group?

A

because the valence electron is further away from the nucleus and therefore less strongly attached

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13
Q

what happens to ionisation energy across a period?

A

increases

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14
Q

why does ionisation energy increase across a period?

A

increase in nuclear charge across the period

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15
Q

what is electron affinity

A

enthalpy change when one electron is added to each atom in one mole of gaseous atoms

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16
Q

what happens to electron affinity down a group?

17
Q

what happens to electron affinity across a period

A

becomes more exothermic

18
Q

why does electron affinity become more exothermic across a period

A

an increase in nuclear charge and a decrease in atomic radius from left to right

19
Q

what is electronegativity?

A

a measure of the attraction of an atom in a molecule for the electron pair in the covalent bond

20
Q

what happens to electronegativity down a group

21
Q

what happens to electronegativity across a period?

22
Q

why does electronegativity decrease down a group

A

the size of the atom increases so the bonding pair is further away from the nucleus

23
Q

why does electronegativity increase across a period

A

increase in nuclear charge across a period with no change in shielding

24
Q

what are group 1 elements known as?

A

alkali metals

25
what are properties of alkali metals?
highly reactive, soft, low melting point
26
what happens to melting point down group 1
decreases
27
what determines the reaction of an element?
the number of valence elevctrons
28
how do group 1 elements react with oxygen?
react vigorously with oxygen and tarnish rapidly in the air
29
how do group 1 elements react with water?
react rapidly with water forming a metal hydroxide
30
what are group 17 elements known as
halogens
31
what happens to the melting point going down group 17
melting point increases
32
why does melting point increase down group 17
london forces between molecules increase therefore more energy must be supplied to separate the molecules
33
what does a amphoteric oxide react with
acids and bases
34
what can oxides be classified as?
basic, acidic, amphoteric