chapter 3 Flashcards

1
Q

how are elements in the periodic table arranged?

A

in order of increasing atomic number

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2
Q

what is metallic structure

A

a lattice of positive ions in a sea of delocalised electrons

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3
Q

what happens to ionisation energy down a group

A

ionisation energy decreases

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4
Q

properties of metallic elements

A

large atomic radii, low ionisation energy, less exothermic electron affinity and low electronegativity

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5
Q

what are electrons in the outer shell known as?

A

valence electrons

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6
Q

how is the periodic table divided

A

in to blocks (s,p,d,f,g)

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7
Q

what is atomic radius?

A

used to describe the size of an atom

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8
Q

what happens to atomic radius down a group?

A

it increases

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9
Q

what happens to atomic radius across a period?

A

decreases

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10
Q

what is ionic radius?

A

a measure of the size of an ion

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11
Q

what happens to ionisation energy down a group?

A

decreases

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12
Q

why does ionisation energy decrease down a group?

A

because the valence electron is further away from the nucleus and therefore less strongly attached

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13
Q

what happens to ionisation energy across a period?

A

increases

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14
Q

why does ionisation energy increase across a period?

A

increase in nuclear charge across the period

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15
Q

what is electron affinity

A

enthalpy change when one electron is added to each atom in one mole of gaseous atoms

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16
Q

what happens to electron affinity down a group?

A

decreases

17
Q

what happens to electron affinity across a period

A

becomes more exothermic

18
Q

why does electron affinity become more exothermic across a period

A

an increase in nuclear charge and a decrease in atomic radius from left to right

19
Q

what is electronegativity?

A

a measure of the attraction of an atom in a molecule for the electron pair in the covalent bond

20
Q

what happens to electronegativity down a group

A

decreases

21
Q

what happens to electronegativity across a period?

A

increases

22
Q

why does electronegativity decrease down a group

A

the size of the atom increases so the bonding pair is further away from the nucleus

23
Q

why does electronegativity increase across a period

A

increase in nuclear charge across a period with no change in shielding

24
Q

what are group 1 elements known as?

A

alkali metals

25
Q

what are properties of alkali metals?

A

highly reactive, soft, low melting point

26
Q

what happens to melting point down group 1

A

decreases

27
Q

what determines the reaction of an element?

A

the number of valence elevctrons

28
Q

how do group 1 elements react with oxygen?

A

react vigorously with oxygen and tarnish rapidly in the air

29
Q

how do group 1 elements react with water?

A

react rapidly with water forming a metal hydroxide

30
Q

what are group 17 elements known as

A

halogens

31
Q

what happens to the melting point going down group 17

A

melting point increases

32
Q

why does melting point increase down group 17

A

london forces between molecules increase therefore more energy must be supplied to separate the molecules

33
Q

what does a amphoteric oxide react with

A

acids and bases

34
Q

what can oxides be classified as?

A

basic, acidic, amphoteric