chapter 3 Flashcards
how are elements in the periodic table arranged?
in order of increasing atomic number
what is metallic structure
a lattice of positive ions in a sea of delocalised electrons
what happens to ionisation energy down a group
ionisation energy decreases
properties of metallic elements
large atomic radii, low ionisation energy, less exothermic electron affinity and low electronegativity
what are electrons in the outer shell known as?
valence electrons
how is the periodic table divided
in to blocks (s,p,d,f,g)
what is atomic radius?
used to describe the size of an atom
what happens to atomic radius down a group?
it increases
what happens to atomic radius across a period?
decreases
what is ionic radius?
a measure of the size of an ion
what happens to ionisation energy down a group?
decreases
why does ionisation energy decrease down a group?
because the valence electron is further away from the nucleus and therefore less strongly attached
what happens to ionisation energy across a period?
increases
why does ionisation energy increase across a period?
increase in nuclear charge across the period
what is electron affinity
enthalpy change when one electron is added to each atom in one mole of gaseous atoms
what happens to electron affinity down a group?
decreases
what happens to electron affinity across a period
becomes more exothermic
why does electron affinity become more exothermic across a period
an increase in nuclear charge and a decrease in atomic radius from left to right
what is electronegativity?
a measure of the attraction of an atom in a molecule for the electron pair in the covalent bond
what happens to electronegativity down a group
decreases
what happens to electronegativity across a period?
increases
why does electronegativity decrease down a group
the size of the atom increases so the bonding pair is further away from the nucleus
why does electronegativity increase across a period
increase in nuclear charge across a period with no change in shielding
what are group 1 elements known as?
alkali metals