Chapter 3 Flashcards

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1
Q

metabolism

A

the sum of all chemical reactions in a cell or organism. Life requires a continual supply of energy.
Catabolic + anabolic

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2
Q

kinetic energy

A

the energy of motion

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3
Q

potential energy

A

the stored energy that an object possesses relative from some 0 position

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4
Q

first law of thermodynamics

A

principle that states that energy can be transferred or transformed, but it cannot be created or destroyed

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5
Q

bond energy

A

the minimum amount of energy that is required to break a particular type of bond; measured in kJ/mol

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6
Q

activation energy (Ea)

A

the minimum amount of energy that chemical reactants must absorb to start a reaction

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7
Q

transition state

A

a temporary condition during a chemical reaction in which the bonds in the reactants are breaking and the bonds in the products are forming

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8
Q

exothermic reaction

A

a chemical reaction in which potential energy is released, leaving the products with less chemical potential energy than the reactants

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9
Q

endothermic reaction

A

a chemical reaction in which energy is absorbed, giving the products more chemical potential energy than the reactants

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10
Q

second law of thermodynamics

A

The randomness (entropy) of a system is always increasing

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11
Q

entropy

A

a measurement of disorder in a system

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12
Q

spontaneous change

A

a change that will, once begun, continue on its own under a given set of conditions; does not require a continuous supply of energy

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13
Q

Free energy

A

energy that can do useful work; also called Gibbs free energy

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14
Q

exergonic reaction

A

a chemical reaction that releases free energy; the products have less free energy than the reactants “spontaneous” “catabolic” (-G value)

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15
Q

endergonic reaction

A

a chemical reaction that absorbs free energy; the products have more free energy than the reactants “non spontaneous” “anabolic” (+G)

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16
Q

energy coupling

A

the transfer of energy from one reaction to another in order to drive the second reaction

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17
Q

catabolic pathway

A

a pathway in which energy is released and complex molecules are broken down into simple molecules

18
Q

anabolic pathway

A

a pathway in which energy is supplied to build complex molecules from simple molecules

19
Q

ATP

A

Adenosine triphosphate consists of adenine, 3 phosphate groups and a 5 carbon sugar called ribose

Universal energy currency in living organisms

Regenerated from ADP and H+ during the ATP cycle

20
Q

Phosphorylation

A

Transfer of a phosphate group, usually from ATP to another molecule

21
Q

ATP hydrolysis

A

an be coupled to endergonic reactions using energy coupling, it releases a lot of free energy and results in the formation of ADP and H+ (Pi)

30.5 KJ/ is are coupled

Bonds are broken down by a catalyzed reaction with H2O

22
Q

ATP cycle

A

The cyclic and ongoing breakdown and re- synthesis of ATP

23
Q

Maud Menten

A

Michaelis- menten euqation states that the rate of an enzyme catalyzed reaction is proportional to the enzyme substrate complexity

24
Q

How does a reaction happen

A

First, all the bonds in the reactants have to break and do to do this they have to be under the correct conditions to overcome the activation energy barrier

25
Q

How do enzymes speed up reactions

A

They lower the activation energy

26
Q

G

A

free energy

27
Q

Why can organisms grow and create internal order without violating the second law of thermo dynamics

A

Organisms can grow and create internal order because living cells can expend order to organize disorganized cells just like humans can expend energy to organize a messy room

28
Q

How does the structure of an ATP molecule relate to the large amount of free energy is possesses

A

The negatively changes PO4 groups are held together by weak bonds leading to a high level of energy

29
Q

dehydrogenase

A

enzyme, oxidizes a substrate and transfers hydrogen atoms to an acceptor

30
Q

NADH

A

Reduced form of the coenzyme nicotinamide adenine dinucleotide

31
Q

What makes a good fuel

A

C-H bonds because they lead to high potential energy

32
Q

Energy change in a redox reaction

A

The electrons are pulled towards the highly electronegative ion

33
Q

Why is controlled oxidation better than rapid consumption

A

It looses less energy and is safer

34
Q

When does entropy increase

A

Solids react to form liquids or gasses

liquids react to form gasses

The total number of product molecules is greater than the total number of reactant molecules

35
Q

Work

A

Work is preformed when energy is used

36
Q

Why do glucose and gasoline make good fuels

A

C-H bonds. They realize a lot of energy as they are pulled closer to atoms with larger nuclei

37
Q

What type of reaction is cellular respiration

A

Combustion of glucose

38
Q

Oxidizing agent on the combustion of glucose

A

O2

39
Q

Reducing agent in the combustion of glucose

A

Glucose

40
Q

What can the waste energy released during cellular redox reactions be used for

A

Cellular processes

41
Q

Slow oxidation events

A

Rotting of fruits and formation of paranoia on copper roofs

42
Q

Rapid oxidizing events

A

Road flare and bring of gasoline