Chapter 3 Flashcards
Wavelength
is the distance between identical points on successive waves
Wave
vibrating disturbance by which energy is transmitted
Amplitude
the vertical distance from the midline of a wave to the peak or trough
Frequency (v)
the number of waves that pass through a particular point in 1 second
Speed (c)
the number of cycles (wavelengths) per second times the wavelength
speed of light
3.00 x 10^8 m/s
Interference
interaction between two or more waves
Diffraction
bending of a wave that occurs when wave encounters object of comparable size to wavelength
Quantum
the smallest quantity of energy that can be emitted(or absorbed) in the form of electromagnetic radiation
Planck’s constant
6.63 x 10^34 J/s
Photons
small bundles of light
Bohr Model Issues
Model works only for one electron systems:
– H atom
– He+, Li2+, Be3+
Fails with poly electron systems because doesn’t account for:
– Additional nucleus/ electron attractions
– Electron repulsions
Quantum Numbers
- Principle quantum number, n
- Angular momentum quantum number, l
- Magnetic quantum number, ml
- Electron spin quantum number, ms
electron configuration
1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d < 5p < 6s
Hund’s Rule
lowest energy configuration for an atom is having the maximum number of unpaired e- allowed by the Pauli exclusion principle in a particular set of degenerate orbitals
Pauli Exclusion Principle
in a given atom, every electron must have a unique set of four quantum numbers
Paramagnetic
Atom has unpaired electrons
Parallel spins
Diamagnetic
All electrons paired
Cation is always smaller than atom from which it is formed
Anion is always larger than atom from which it is formed
Ionization energy
the energy required to remove an electron from the gaseous state of an atom or an ion
Electron affinity
the negative of the energy change that occurs when an electron is accepted by an atom in the gaseous state to form an anion
The closer an e- can be moved to the nucleus, the greater the electron affinity
atomic size
increase left and down
ionization energy
increases up and right
electron affinity
increases up and right