Chapter 2.5 +2.6 - Shifting equilibrium position / Le Chatelier's principle and conc. changes ✓ Flashcards
What are the three main imposed changes that affect equilibrium?
-Changing the concentration of a species
-Changing the total pressure (in a gaseous system)
-Changing the temperature
What does Le Chatelier’s Principle predict?
It predicts how an equilibrium system will respond to imposed changes but does not explain why.
What is Le Chatelier’s Principle?
If a system at equilibrium experiences a change in conditions, it will adjust to establish a new equilibrium that partially counteracts the imposed change
What does “partially counteracts” mean in Le Chatelier’s Principle?
The system responds to an imposed change by shifting equilibrium to reduce its effect, but not completely reverse it.
What happens if more reactants are added to a system at equilibrium?
The equilibrium will shift toward the products to partially counteract the increase in reactants.
What two concepts can be used to explain equilibrium shifts?
Reaction rate and collision theory.
What happens to the system while equilibrium is being re-established?
The system is temporarily out of equilibrium but will eventually return to a new equilibrium state.