Chapter 24: Carbohydrates Flashcards
1
Q
A
Aldose
2
Q
A
Ketose
3
Q
A
Anomeric carbon
4
Q
Anomeric carbon UP =
A
Beta
5
Q
Anomeric Carbon DOWN =
A
Alpha
6
Q
If stereochem around anomeric carbon goes clockwise =
A
R (D)
7
Q
If stereochem around anomeric carbon goes counter-clockwise =
A
S (L)
8
Q
For Fischer: If OH group on anomeric carbon is on the right side =
A
R (D)
9
Q
For Fischer: If OH is on left side on anomeric carbon =
A
S (L)
10
Q
Equation for determining stereoisomers
A
2n= # of stereoisomers
where n= # of stereocenters
11
Q
Muta-Rotation
A
12
Q
Isomerism
A
13
Q
Glycoside Formation
A
14
Q
Methylation
A
15
Q
Acetylation
A
16
Q
Oxidation
A
17
Q
Reduction
A
18
Q
Kiliani-Fischer Synthesis
A
