Chapter 23: Amines Flashcards
1
Q
Amine classifications
A
2
Q
Deprotonated amines are called ____
A
amides
3
Q
Attempting to synthesize primary amines from alkyl halides via SN2 results in formation of ___
A
quarternary ammonium salts
4
Q
Gabriel synthesis
A
- use of phthalimide dummy group
- can be further reacted to release primary amine
5
Q
Releasing amine:
A
acid-catalyzed release
6
Q
Releasing amine:
A
using hydrazine
7
Q
Reductive Amination
A
Ketone to 2o amine
8
Q
Acylation of Amines
A
9
Q
De-acylation of amines (amides?)
A
10
Q
Preparing Nitrous Acid
A
11
Q
Hydrolysis of nitrous acid
A
12
Q
Secondary Amine with nitrousonium ion
A
13
Q
Primary amine with nitrousonium ion
A
14
Q
A
15
Q
A
16
Q
A
17
Q
A
18
Q
A
19
Q
A
20
Q
Hoffman elimination
A
21
Q
Bromination (E.A.S.)
A
22
Q
Nitration (E.A.S.)
A
23
Q
Reduction of R-NO2
A
24
Q
Hoffman Rearrangement
A
25
Q
Curtius Rearrangement
A
