Chapter 23 Hazmat Flashcards
TRACEM - 6 haz mat hazard types
Thermal Radiological Asphyxiation Chemical Etiological/biological Mechanical
Polymerization
Chem reaction, two molecules combine to form larger molecules. Can be violent reaction
Elevated temp material
liquid above 100C (212F)
intentionally heated above liquid phase flash point of 38C
Solids above 240C
Cryogens
Gases that convert to liquids when cooled at or below -90C at 14.7 psi (101kPa)
Nitrogen helium hydrogen argo liquid oxygen and liquidified natural gas
Poison
Anything injurious to health when taken into body
Ionizing radiation
Causes chem change in atoms by removing electrons (ionizing most energetic, non ionizing least energetic)
Radiological hazards
Most common at med centers nuclear power plants research facilities and transport incidents
Nonionizing radiation
Energy waves composed of oscillating electric and magnetic fields traveling at speed of light - incluide visible light, radio waves, microwaves, infrared radiation and ultraviolet radiation
Ionizing radiation
Alpha
Proton/electron
Positive/negative charge
Photon
Weightless packet of electromagnetic energy such as x-ray or visible light
Alpha radiation
In smoke detectors
Stopped by skin
Don’t put it in your mouth
Beta radiation
Can make it 20 ft through air, but then are stopped by clothes
Gamma radiation
Easily pass through body Stopped by 2 inches of lead 2 feet concrete Several feet of earth Firefighting clothing does shit all
Neutron radiation
Fission reactions and oil moisture density gauges
Mass but no electric charge
Creates secondary radiation
Corrosive
Corrodes steel. Damages human tissue
Divided into acid and base’s (not all are acids or bases like peroxide)
Asphyxiants
Simple displaced air
Chemical is CO and cyanide
Ion
Atom that has lost or gained an electron, giving it a charge
pH
Acid immediate pain. Corrosive action gives off lots of heat
Bases 8-14. Not usually immediate. They stick to eye tissue and breakdown fat. Skin may feel greasy or slick after exposure
HCL an react with metal to form explosive hydrogen gas
Acids and bases can react violently to water
Convulsants
For this it means muscle contractions
Carcinogens
PVC benzene asbestos arsenic nickel some pesticides some chlorinated hydrocarbons and many plastics
Biological hazards
Also called etiological
Rickettsias are bacteria on lice fleas and ticks
Infection can transmit to people
Contagious is person to person
Explosion three hazards
Blast pressure - most of injuries and damage
Shrapnel
Seismic effects
Lighter than air gasses
4H’s MEDIC ANNA
Hydrogen Helium Hydrogen cyanide (1.0) Hydrogen fluoride Methane Ethylene Diborane Illuminating gases CO (0.96) Acetylene Neon Nitrogen Ammonia
Vapour pressure
Tendency to evaporate
Rises as temp increases
Boiling point
Temp at which vapour pressure is equal or greater to atmospheric pressure
Flammable liquids with low boiling points are more dangerous
Vapour density
Less than one rises
Specific gravity
Less than one floats
Strong oxidizers
Readily give off oxygen to sustain a reaction
Hydrocarbons can ignite spontaneously when mixed with one such as nitrates perchlorate a chlorine and fluorine
General emergency behaviour model GEBMO
Six stages of events at an incident Stress Breach Release Dispersion Exposure Harm
GEBMO three types of stress
Thermal
Chemical
Mechanical
GEBMO breach types
Disintegration- glass bottle shattering or grenade exploding Cracking Attachments open or break Puncture Split or tear
GEBMO release types
Detonation
Violent rupture
Rapid relief
Spill