Chapter 2 Objectives Flashcards
atomic number
The number of protons in an element
atomic mass
The sum of the number of protons and neutrons in the atom.
isotope
An element that has the same number of protons but a different number of neutrons
radioactive isotope
The ratio of protons to isotopes can cause for an unstable nucleus that is not as firmly held together due to the different number of protons.
electron shell
The orbitals of the atom where the electrons are located in different levels numbered 1, 2, 3 and so on to indicate their proximity to the nucleus. Each shell can contain a specific number of electrons
Valence shell
the outermost shell of the atom
Valence electron
the electron(s) found in the outermost shell
Valence
The number of unpaired electrons in the outermost electron shell of an atom; determines how many covalent bonds the atom can form.
covalent bond
the bonds formed when atoms share two valence electrons. Covalent bonds can be polar or nonpolar according to the electronegativity of the elements involved and how much they evenly share the electrons.
organic compounds
Organic compounds are covalent compounds that contain carbon and hydrogen. They might also contain smaller amounts of other elements such as sulfur, phosphorous, or any of the halogens.
ionic bond
One element loses an electron while another gains an electron, causing ions (charged atoms) that then bond to each other due to their opposite charges.
Cation is positively charged
anion is negatively charged
hydrogen bond
Bonds that form because opposite, partial electric charges on polar molecules attract. (dipole dipole interaction)
Why is a hydrogen bond weaker than a covalent bond?
The dipole dipole interaction of partially charged molecules is not as strong as the interaction
Van der Waals interactions
A weak electrical attraction between two hydrophobic side chains. Often contributes to tertiary structure in proteins.
mole
The amount of a substance that contains 6.022 x10^23 of an element. It also equals the molecular weight of a compound in grams.
molecular weight
The molecular weight is the sum of the mass numbers of all the atoms in the molecule.
molarity
The number of moles of the substance present per liter of solution.
energy
capacity to do work
What are the two major categories of energy?
Kinetic (constant motion) and potential energy (stored energy)
What type of energies do molecules have?
Molecules have kinetic energy because they are constantly in motion. The kinetic energy of molecular motion is called thermal energy.
entropy (S)
the amount of disorder in a group of molecules
When products of a chemical reaction are less ordered than the reactant molecules, entropy increases and ΔS is positive. Spontaneous reactions tend to increase entropy.
generally, physical and chemical processes proceed in the direction that results in lower potential energy and increased disorder
ΔG
Gibbs free-energy change - used to determine whether a reaction is spontaneous by assessing the combined contributions of changes in heat and disorder
ΔG = ΔH - TΔS
When ΔG is less than zero, chemical reactions are spontaneous
exergonic
when chemical reactions are spontaneous and ΔG is less than zero
endergonic
Non-spontaneous chemical reactions and ΔG is greater than zero.