Chapter 2 Characteristics of Semiconductor Materials Flashcards
Classifying Materials
Three different materials based on the flow of electric current through those materials: Conductors, Insulators, and Semiconductors.
Conductors
Electrons readily flow through the material, high current-carrying capability. Carry one electron in valence shell that is easily free to conduct electricity.
Conductivity Resistivity
Depends on material not geometry.
Resistance
Opposition to current flow.
Insulator
High resistance to current flow; rubber, plastic, glass, and ceramics. Typical insulating materials in semiconductors. (SiO2, Si3N4)
Capacitance
Storage of electrical charge. Spacing between plates.
Semiconductors
Can function as either conductors or insulators. Silicon is the most important material because 85% of all chips use silicon wafer substrate.
How Semiconductors work?
Energy band gaps of insulators, conductor, and semiconductor.
Electrons in semiconductor jump from the valence band into the conduction bend when energy is supplied.
Why Silicon?
- Abundance of silicon 25% of earth crust.
- Higher melting temperature: 1412 C wide processing range.
- Wider temperature range of operation: increase in application and reliability.
- Natural growth of SiO2: chemical barrier to protect Si from external contamination.
Doping
Is the process of adding certain elements to pure silicon to enhance its material properties; conductivity or resistivity.
Doping Materials
Silicon is located in group 4A of the periodic table and has four valence electrons. Elements from the two adjacent groups are commonly used for doping: Group 3A (Boron) and 5A (Nitrogen).
Group III A
Trivalent: 3 valence electrons, increase number of holes for positive doping or p-type.
Group VA
Pentavalent: 5 valence electrons, increase the number of free electrons for negative doping or n-type.
Resistivity of Doped Silicon
Depends on the concentration of the dopants, there is less concentration of n-type than p-type. Takes less energy to move an electron than to move a hole.