Chapter 18 Flashcards

1
Q

Fires and explosions result of

A

combustion

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2
Q

Combustion

A

Reaction of fuel with oxygen

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3
Q

products of combustion

A

CO2
water
energy

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4
Q

Exothermic

A

chemical reaction releases energy as product

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5
Q

Endothermic

A

required input of energy

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6
Q

Activation energy

A

reaction require some input of energy for initial on

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7
Q

fire tetrahedron

A

oxygen
heat
fuel
chain reaction

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8
Q

flash point

A

lowest temp allow liquid produce a flammable vapor

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9
Q

flame point

A

lowest temp that will sustain combustion

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10
Q

flashback

A

fire burned with limited supply of oxygen then suddenly ventilated

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11
Q

Types of fire

A

natural
accidental
deliberate

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12
Q

first step of analysis

A

isolate the accelerant from matrix

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13
Q

second step

A

determine nature of accelerant

GC or MS

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14
Q

Headspace

A

sampled with gaslight syringe and injected into GC

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15
Q

passive adsorption

A

container or strip coated with charcoal places in suspected container

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16
Q

active absorption

A

charcoal tubes inserted and air pumped through tubes into container

17
Q

Solid Phase micro extraction

A

inserting fiber with adsorbent into headed container

GC

18
Q

Mass spectrometry

A

individual components of residues

19
Q

blast pressure

A

escaping gases
pressure wave
vacuum created

20
Q

low explosives

A

below 3,280 fps

21
Q

high explosives

A

3,280 psi and up

22
Q

high order explosion

A

at least near its maximum theoretical detonation velocity

23
Q

low order explosion

A

less than optimal efficiency

24
Q

low explosive trains

A

two step

fuse black powder used to ignite smokeless powder

25
Q

high explosives trains

A

final is usually secondary

blasting calps

26
Q

two types of residue

A

undetonated and exploded

27
Q

vapor trace analyzer

A

find explosive residues

GC

28
Q

How visual examination works

A

isolates explosive residues from matrix

29
Q

thin layer chromatography

A

color reagents

30
Q

high performance liquid chromatography

A

quantitative analysis

31
Q

Infrared spectrophotometry

A

confirmatory test