Chapter 15 Flashcards

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1
Q

In an isothermal process, there is no change in ________

A

temperature

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2
Q

A gas is expanded to twice its original volume with no change in its temperature. This process is ________

A

isothermal

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3
Q

An ideal gas is compressed to one-half its original volume during an isothermal process. The final pressure of the gas ________

A

increases to twice its original value

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4
Q

A gas is quickly compressed in an isolated environment. During the event, the gas exchanged no heat with its surroundings. This process is ________

A

adiabatic

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5
Q

The process shown on the PV diagram is an ________

A

isobaric expansion

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6
Q

When water freezes, the entropy of the water ________

A

decreases

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7
Q

During an isothermal process, 5.0 J of heat is removed from an ideal gas. What is the change in internal energy of the gas?

A

zero

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8
Q

During an isothermal process, 5.0 J of heat is removed from an ideal gas. What is the work done by the gas in the process?

A

-5.0 J

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9
Q

An ideal gas undergoes an adiabatic process while doing 25 J of work. What is the change in internal energy?

A

-25 J

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10
Q

A heat engine receives 7000 J of heat and loses 3000 J in each cycle. What is the efficiency?

A

57%

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11
Q

A heat engine has an efficiency of 35.0% and receives 150 J of heat per cycle. How much work does it perform in each cycle?

A

52.5 J

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12
Q

What is the Carnot efficiency of an engine which operates between 450 K and 310 K?

A

31%

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13
Q

What is the maximum theoretical efficiency possible for an engine operating between 100°C and 400°C?

A

45%

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14
Q

What is the change in entropy when 50 grams of ice melt at 0°C?

A

60.9 J/K

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15
Q

What is the change in entropy when 100 g of water at 10°C is mixed with 100 g of water at 40°C?

A

1.0 J/K

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16
Q

What is the change in entropy when 1 kg of water at 0°C is mixed with 3 kg of water at 20°C?

A

7.7 J/K

17
Q

1.0 kg of steam at 100°C condenses to water at 100°C. What is the change in entropy in the process?

A

-6.1 x 10^3 J/K

18
Q

On a very hot day, could you cool your kitchen by leaving the refrigerator door open?

A

No, the refrigerator would exhaust more heat into the room than it takes out of the room.

19
Q

In the closed thermodynamic cycle shown in the PV diagram, the total work done by the gas during a complete cycle is:

A

postive

clockwise closed cycle = positive total work
counter-clockwise closed cycle = negative total work

20
Q
A
21
Q

A heat engine exhausts 7800 J of heat while performing 2600 J of useful work. What is the efficiency of this engine?

A
22
Q

Which of the following is the best example of a reversible process?

A

A block of metal surrounded by water at a slightly higher temperature slowly heats up.

  • a reversible process is carried out slow enough that is could be considered a series of equilibrium states
23
Q

A Carnot engine’s operating temperatures are 210°C and 45°C. The engine’s power output is 950 W. Calculate the rate of heat output.

A
24
Q
A

an irreversible heat engine

*efficiency is smaller than the Carnot engine efficiency so it must be an irreversible heat engine

25
Q

A restaurant refrigerator has a coefficient of performance of 5.0. If the temperature in the kitchen outside the refrigerator is 32°C, what is the lowest temperature that could be obtained inside the refrigerator if it were ideal?

* Coefficient of performance (COP)

A
26
Q

What is the COP of a Carnot heat pump used to remove heat from ice at 0.0°C and add heat to a room at 20.0°C?

A

14.7

293 K/20 K = 14.7

27
Q

Totoal change in entropy for a reversible process is:

A

zero

28
Q

If 0.45 kg of water at 100°C is changed by a reversible process to
steam at 100°C, determine the change in entropy of (a) the water, (b) the surroundings, and (c) the universe as a whole. (d) How would your answer differ if the process were irreversible?

A
29
Q

The second law of thermodynamics leads us to conclude that:

A

disorder in the universe is increasing with the passage of time.

30
Q

If two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium with each other

A

Zeroth Law

31
Q

The change in internal energy of a system equals the heat that
flows into or out of it minus the work done by the system (conservation of energy)

A

First Law

32
Q

For any real process, the entropy of any isolated system always increases

A

Second Law

33
Q

The entropy of a system approaches a constant minimum value as the temperature approaches absolute zero.

A

Third Law

*absolute zero is impossible to reach through real processes