Chapter 14 solutions Flashcards

1
Q

Define solvent

A

Greatest quantity in a component

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2
Q

Define solute

A

Rest of the minority in a component

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3
Q

How does entropy affect solution

A

A solution forms as a substance disperses through the solution

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4
Q

What is a condensed phases

A

Gaseous mixtures involve substance to be condensed

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5
Q

Of the two forces
Ion-dipole forces & London disp.forces which dominate ionic/polar solutions and the other dominate nonpolar solutions?

A

Ion-dipole forces dominate ionic /polar solutions
London dispersion forces dominate nonpolar solutions

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6
Q

Define solute -solute interactions

A

Attractive forces hold solids together

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7
Q

Define solvent - solute forces

A

Attractive forces between water and what ever solid particles

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8
Q

Define solvated

A

When solvent molecules surround and interact with solute ions

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9
Q

When are ionic solute encased in solvation sphere?

A

When they are solvated

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10
Q

What’s the sign for enthalpy

A

∆ H

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11
Q

What’s the sign for entropy

A

∆ S

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12
Q

Is solution formation physical or chemical?

A

Physical
Chemical reactions can lead to a solution but only after a chemical reaction has occurred

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13
Q

How does crystallization form

A

When a solid dissolves its concentration ⬇️ when solute ions colliding with one another to form

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14
Q

What does to mean when a solution is saturated?

A

It has reached a equilibrium it needs to reach solubility

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15
Q

Define solubility

A

Amount of a compound that dissolves in a particular amount of liquid

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16
Q

Define solution

A

The maximum amount of solute under certain conditions

17
Q

Define unsaturated solution

A

One holding less than the maximum amount of solute

18
Q

How does temperature affect solute?

A

It can under special conditions dissolve the solute

19
Q

Define miscible

A

The ability of a liquid to completely dissolve in another.
Polar liquids in polar solvents

20
Q

Define immiscible

A

Liquid never fully mix with one another
Nonpolar liquids in polar solvents

21
Q

Are polar liquid immiscible in non polar solvent?

A

Yes

22
Q

Does solubility in water decrease or increase with increasing temperature?

A

Increase

23
Q

Does solubility of gas in water increase or decrease with increasing temperature?

A

Deceeases

24
Q

How does pressure affect solubility?

A

Increased pressure at vapor pressure = ⬆️ soluble gas in liquid

25
Q

Define mass %

A

Expressed by dividing mass of component in solution by the mass of solution (x100%)

26
Q

Define mole fraction

A

Moles of components / total moles of all components

27
Q

Define molarity

A

Mol solute /L solution

28
Q

Define molality

A

Mol solute / kg solvent , depends on mass of solvent and does not vary w/temperature

29
Q

Define molality

A

Mol solute / kg solvent , depends on mass of solvent and does not vary w/temperature

30
Q

Define Colligative properties

A

Properties that depend on the concentration of the solute ions , not the identity of the solute

31
Q

Define lowering vapor pressure

A

Adding nonvolatile solute to a solvent to lower vapor pressure

32
Q

Define boiling point elevation

A

Normal boiling point for a liquid is the temperature at which the vapor pressure equals 1atm. A higher temp = vapor pressure of 1 atm

33
Q

Define is osmotic pressure

A

Driven by solute - solvent interactions