Chapter 14 solutions Flashcards
Define solvent
Greatest quantity in a component
Define solute
Rest of the minority in a component
How does entropy affect solution
A solution forms as a substance disperses through the solution
What is a condensed phases
Gaseous mixtures involve substance to be condensed
Of the two forces
Ion-dipole forces & London disp.forces which dominate ionic/polar solutions and the other dominate nonpolar solutions?
Ion-dipole forces dominate ionic /polar solutions
London dispersion forces dominate nonpolar solutions
Define solute -solute interactions
Attractive forces hold solids together
Define solvent - solute forces
Attractive forces between water and what ever solid particles
Define solvated
When solvent molecules surround and interact with solute ions
When are ionic solute encased in solvation sphere?
When they are solvated
What’s the sign for enthalpy
∆ H
What’s the sign for entropy
∆ S
Is solution formation physical or chemical?
Physical
Chemical reactions can lead to a solution but only after a chemical reaction has occurred
How does crystallization form
When a solid dissolves its concentration ⬇️ when solute ions colliding with one another to form
What does to mean when a solution is saturated?
It has reached a equilibrium it needs to reach solubility
Define solubility
Amount of a compound that dissolves in a particular amount of liquid
Define solution
The maximum amount of solute under certain conditions
Define unsaturated solution
One holding less than the maximum amount of solute
How does temperature affect solute?
It can under special conditions dissolve the solute
Define miscible
The ability of a liquid to completely dissolve in another.
Polar liquids in polar solvents
Define immiscible
Liquid never fully mix with one another
Nonpolar liquids in polar solvents
Are polar liquid immiscible in non polar solvent?
Yes
Does solubility in water decrease or increase with increasing temperature?
Increase
Does solubility of gas in water increase or decrease with increasing temperature?
Deceeases
How does pressure affect solubility?
Increased pressure at vapor pressure = ⬆️ soluble gas in liquid
Define mass %
Expressed by dividing mass of component in solution by the mass of solution (x100%)
Define mole fraction
Moles of components / total moles of all components
Define molarity
Mol solute /L solution
Define molality
Mol solute / kg solvent , depends on mass of solvent and does not vary w/temperature
Define molality
Mol solute / kg solvent , depends on mass of solvent and does not vary w/temperature
Define Colligative properties
Properties that depend on the concentration of the solute ions , not the identity of the solute
Define lowering vapor pressure
Adding nonvolatile solute to a solvent to lower vapor pressure
Define boiling point elevation
Normal boiling point for a liquid is the temperature at which the vapor pressure equals 1atm. A higher temp = vapor pressure of 1 atm
Define is osmotic pressure
Driven by solute - solvent interactions