Chapter 13 in class lecture: Flashcards

1
Q

What is the equation for molality?
What is molality used for?
what is the symbol for molality

A

moles of solute/ kg of solution

  1. ) volume tends to change with temp, and molality is useful for colligative properties
  2. ) m
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2
Q

how to solve for mol fraction?
what is the abbreviation of a mol fraction?
when is a mol fraction most commonly used?

A
  • mols of desired component of mixture/ total # of mols in the mixture.
  • (x)
  • to find partial pressures of gases.
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3
Q

How to solve for mass %?

A

(mass of desired component/ total mass of solid) * 100%

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4
Q

What is PPM?

What is the equation for PPM?

A

Parts per million

(mass of desired component/ total mass of solid) x 10 ^6

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5
Q

What is PPB?

What is the equation for PPB?

A

Parts per billion

(mass of desired component/ total mass of solid) x 10 ^9

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6
Q

What is true of the solubility of solids?

A

solubility increases as temperature

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7
Q

What is true of the solubility of gases?

A

solubility of gas in a solution is proportional to the pressure of the gas above the solution

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8
Q

What is Henry’s Law?

A

solubility of a gas in a solution is equal to: K x P
K= proportionality constant
P= proportionality constant (specific to any given gas)

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9
Q

What are colligative properties?

A

properties that depend only on the amount of of stuff dissolved in the solution, not on the identity of the stuff.

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10
Q

What are the colligative properties?

A
  1. ) vapor pressure lowering/depression
  2. ) Freezing point depression
  3. ) Boiling elevation
  4. ) Osmotic pressure
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11
Q

What equation do you use for vapor pressure lowering?

A

Raoult’s law: P(solution)= P(solvent) * xXsolvent

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12
Q

Partial Pressure?

A

{Pressure(substance * mols(substance)} +{Pressure(substance * mols(substance)} + {Pressure(substance * mols(substance)}

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13
Q

What happens to vapor pressure as you add more stuff to the solution?

A

It lowers

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14
Q

What is the Van’t Hoff factor of a covalent bond if it isn’t stated in the problem?

A

1

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15
Q

What is the Van’t Hoff factor of a ionic bond if it isn’t stated in the problem?

A
  • the amount of individual atoms or polyatomic ions the substance breaks down into
  • Ex: NaCl = I = 2
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16
Q

Describe the process of determining the vapor pressure using the Van’t Hoff Factor:

A
  • 1st you need to get the necessary componets of the problem: mols solute and solvent, Van’t hoff factor, and the pressure of the solute @ T.
  • 2nd: mols solute/mols solv + mols solu X I
  • 3rd: take this number and multiply it by the P(solu) @ T.
17
Q

What is the Equation for Bp elevation:

A
DeltaT(b) = K(b) x m x i
Change in boiling point
Boiling point elevation
molality
Van't Hoff Factor
18
Q

What is the equation for Fp Decline:

A

DeltaT(f) = -K(f) * m * i
change in freezing point
Freezing point depression constant

19
Q

What is the equation for Osmosis/Osmotic pressure?

A
Pi = M * R * T * i
(osmotic pressure)
Molarity
Gas constant 
Temperature
Van't Hoff factor
20
Q

What does it mean to be spontaneous

A

requires no energy to complete