Chapter 12: Physical Properties of Solutions Flashcards
Boiling point elevation
The boiling point of the solution minus the boiling point of the pure solvent
Colligative properties
Properties of solutions that depend on the number of solute particles in solution and not on the nature of the solute particles
colloid
a dispersion of particle on one substance (the dispersed phase) throughout a dispersing medium made of another substance
crystallization
the process in which dissolved solute comes out of solution and forms crystals
fractional crystallization
The separation of a mixture of substances into pure components on the basis of their different solubilities
fractional distillation
A procedure for separating liquid components of a solution that is based on their different boiling points
freezing-point depression
the freezing point of the pure solvent minus the freezing point of the solution
Henry’s Law
the solubility of a gas in a liquid is proportional to the pressure of the gas over the solution
hydrophilic
water liking
hydrophobic
water fearing
ideal solution
any solution that obeys Raoult’s law
ion pair
One or more cations and one or more anions held together by electrostatic forces
miscible
two liquids that are completely soluble in each other in all proportions are said to be miscible
molality
the number of moles of solute dissolved in one kg of solvent
nonvolatile
does not have a measurable vapor pressure
osmosis
the net movement of solvent molecules through a semipermeable membrane from a pure solvent or from a dilute solution to a more concentrated solution
osmotic pressure
the pressure required to stop osmosis
percent by mass
the ratio of the mass of a solute to the mass of the solution, multiplied by 100%
Raoult’s Law
The vapor pressure of the solvent over a solution is given by the product of the vapor pressure of the pure solvent and the mole fraction of the solvent in the solution
Saturated Solution
At a given temperature, the solution that results when the maximum amount of a substance has been dissolved in a solvent
semipermeable membrane
A membrane that enables solvent molecules to pass through, but blocks the movement of solute molecules
solvation
the process in which an ion or molecule is surrounded by solvent molecules arranged in a specific manner
supersaturated solution
a solution that contains more of the solute than is present in a saturated solution
unsaturated solution
a solution that contains less solute than it has the capacity to dissolve
van’t Hoff factor (i)
the ratio of actual number of parcels in solution after dissociation to the number of formula units initially dissolved in solution
Volatile
has measurable vapor pressure