Chapter 12 Flashcards
Age hardening
A special dispersion-strengthening heat treatment. By solution treatment, quenching,
and aging, a coherent precipitate forms that provides a substantial strengthening effect. (Also
known as precipitation hardening.)
Artificial aging
Reheating a solution-treated and quenched alloy to a temperature below the
solvus in order to provide the thermal energy required for a precipitate to form
Athermal transformation
When the amount of the transformation depends only on the temperature,
not on the time (same as martensitic transformation or displacive transformation).
Austenite
The name given to the FCC crystal structure of iron and iron-carbon alloys
Avrami relationship
Describes the fraction of a transformation that occurs as a function of
time. This describes most solid-state transformations that involve diffusion; thus martensitic transformations
are not described.
Bainite
A two-phase microconstituent, containing ferrite and cementite, that forms in steels that
are isothermally transformed at relatively low temperatures
Bake-hardenable steels
These are steels that can show an increase in their yield stress as a result
of precipitation hardening that can occur at fairly low temperatures (100°C), conditions that simulate
baking of paints on cars. This additional increase leads to better dent resistance
Cementite
The hard, brittle ceramic-like compound Fe3C that, when properly dispersed, provides
the strengthening in steels.
Coherent precipitate
A precipitate with a crystal structure and atomic arrangement that have
a continuous relationship with the matrix from which the precipitate is formed. The coherent precipitate
provides excellent disruption of the atomic arrangement in the matrix and provides excellent
strengthening.
Dihedral angle
The angle that defines the shape of a precipitate particle in the matrix. The dihedral
angle is determined by the relative surface energies of the grain boundary energy of the matrix
and the matrix-precipitate interfacial energy.
Displacive transformation
A phase transformation that occurs via small displacements of
atoms or ions and without diffusion. Same as athermal or martensitic transformation
Ferrite
The name given to the BCC crystal structure of iron that can occur as or . This is not
to be confused with ceramic ferrites, which are magnetic materials.
Guinier-Preston (GP) zones
Clusters of atoms that precipitate from the matrix in the early
stages of the age-hardening process. Although the GP zones are coherent with the matrix, they are
too small to provide optimum strengthening.
Interfacial energy
The energy associated with the boundary between two phases.
Isothermal transformation
When the amount of a transformation at a particular temperature
depends on the time permitted for the transformation.
Martensite
A metastable phase formed in steel and other materials by a diffusionless, athermal
transformation.
Martensitic transformation
A phase transformation that occurs without diffusion. Same as
athermal or displacive transformation. These occur in steels, Ni-Ti, and many ceramic materials.
Natural aging
When a coherent precipitate forms from a solution treated and quenched agehardenable
alloy at room temperature, providing optimum strengthening.
Nitinol
A nickel-titanum shape memory alloy.
Pearlite
A two-phase lamellar microconstituent, containing ferrite and cementite, that forms in
steels cooled in a normal fashion or isothermally transformed at relatively high temperatures
Precipitation hardening
See age hardening.
Shape-memory effect
The ability of certain materials to develop microstructures that, after
being deformed, can return the material to its initial shape when heated (e.g. Ni-Ti alloys).
Smart materials
Materials that can sense an external stimulus (e.g., stress, pressure, temperature
change, magnetic field, etc.) and initiate a response. Passively smart materials can sense external
stimuli; actively smart materials have sensing and actuation capabilities.
Solution treatment
The first step in the age-hardening heat treatment. The alloy is heated above
the solvus temperature to dissolve any second phase and to produce a homogeneous single-phase
structure.
Strain energy
The energy required to permit a precipitate to fit into the surrounding matrix during
nucleation and growth of the precipitate.