Chapter 11: Solutions Flashcards
solution
a homogeneous mixture involving two or more substances
solute
the substance that is dissolved in a solution
solvent
the liquid in which the solute dissolves (the major component of the solution)
dilute
low amounts of solute per amount of solution
concentrated
high amounts of solute per amount of solution
concentration
the amount of solute that is present in a solution
saturated solution
a solution contains the maximum amount of dissolved solute in a specific amount of solvent
unsaturated solution
a solution that contains less than the maximum amount of dissolved solute in a specific amount of solvent
supersaturated solution
an unstable condition in which there is more solute present in solution than its solubility would indicate
solubility
a measure of the maximum amount of a solute that dissolves in a specific amount of solvent at a given temperature
miscible liquids
liquids that mix completely to form a solution
immiscible liquids
liquids that do not mix and form separate layers, neither liquids dissolve into the other
“like dissolves like”
nonpolar (or weakly polar) substances are generally soluble in nonpolar solvents & ionic and polar compounds are generally soluble in polar solvents
mass percent
the ratio of the mass of solute that is present in a solution relative to the mass of the solution as a whole; mass of solute / mass of solution * 100%
volume percent (v/v)
the ratio of the volume of solute that is present in a solution relative to the volume of the solution as a whole; volume of solute / volume of solution * 100%
parts per million (ppm)
how many parts a certain molecule or compound makes up within the one million parts of the whole solution; 1 ppm = 1g of solute per 1,000,000 grams of solution or 1 mg/L of solution
parts per million (ppm) formula
mass of solute / mass of solution x 10^6
parts per billion (ppb)
how many parts a certain molecule or compound makes up within the one billion parts of the whole solution; 1 ppb = 1g of solute per 1,000,000,000 grams of solution or 1 Mg/L of solution
parts per billion (ppb) formula
mass of solute / mass of solution x 10^9
molarity (M)
a measure of concentration defined as moles of solute per liter of solution; M = moles of solute (or n) / volume (L)
chemists prepare dilute solutions by
mixing the concentrated solution with additional solvent; doing this increases the volume of the solution, but the moles of the solute do not change
the moles of a solute are equal to
molarity x volume
the concentration of a solute uses
square brackets []
electrolyte solution
an aqueous solution containing dissolved ions
electrolyte concentration
the amount of dissolved ions in a solution, typically expressed in terms of molarity (moles per liter)
colligative properties
properties of a solution that do not depend on the type of particles that are dissolved, but rather on the number of dissolved particles in the solution
three common and important colligative properties
freezing point depression, boiling point elevation, and osmotic pressure
freezing point depression
the presence of solute in an aqueous solution lowers the freezing point below that of pure water (e.g. salt trucks in winter)
in freezing point depression, the more dissolved particles
the lower the freezing temperature
boiling point elevation
the pressure of solute in an aqueous solution raises the boiling point above that of pure water
the boiling point elevation depends on
the number of solute particles present
osmotic pressure
the tendency of water to move toward regions of greater concentration
hypotonic solution
low osmotic pressure solution in which water migrates into the cells, causing them to swell and possibly burst
hypertonic solution
high osmotic pressure solution in which water flows out of the cells, causing them to shrivel
isotonic solution
ideal solution where the concentration is the same both in and outside of the cell
gravimetric analysis
a technique that uses the mass of a precipitate to determine the concentration of a reactant
steps of gravimetric analysis
- measure the volume of the unknown
- precipitate the ion
- filter and dry the precipitate
- measure the mass of the precipitate
metal displacement reaction
a reaction between two metals in which one metal is oxidized to its ionic form while the other metal ion is reduced to its elemental form (single displacement reaction)