Chapter 11 Flashcards

1
Q

what affects vapor pressure in liquids?

A

temp and intermolecular pressure

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2
Q

lattice energy

A

energy released when 1 mol of an ionic compound forms from its free ions in the gas phase

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3
Q

vapor pressure

A

pressure exerted by a gas in equilibrium with liquid

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4
Q

which R do you use with the CC equation?

A

8.3145

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5
Q

what does normal mean?

A

1 atm

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6
Q

how do you find total vapor pressure?

A

mole fraction x partial pressure

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7
Q

colligative properties

A

set of properties of a solution relative to the pure solvent

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8
Q

what are colligative properties dependent on?

A

concentration of solute particles not identity

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9
Q

what is molality?

A

moles over kg of solvent

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10
Q

how does lattice energy affect solubility?

A

large lattice energy means limited solubility

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11
Q

volatile

A

having a significant vapor pressure at a given temp

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12
Q

what is the vapor pressure at a liquids normal boiling point?

A

1 atm

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13
Q

when is a liquid more volatile?

A

when it has a higher vapor pressure

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14
Q

if a solute-solvents interactions are stronger than solvent-solvent, which way does it deviate?

A

negatively (up)

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15
Q

if a solute-solvents interactions are weaker than solvent-solvent, which way does it deviate?

A

positively (down)

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16
Q

examples of colligative properties

A

boiling point elevation and freezing point depression

17
Q

why are theoretical and experimental values on van’t Hoffs factor different?

A

cations and actions cluster together and act as one molecule

this causes the fbd and the bpe to be less than predicted

18
Q

osmotic pressure

A

pressure applied across a semipermeable membrane to stop the flow