Chapter 1 - Chemical foundations Flashcards

0
Q

measurement

A

a quantitative observation

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1
Q

what are the three fundamental steps to the Scientific Method

A

Make observations
formulate hypotheses
perform experiments

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2
Q

what are the necessary components of a measurement?

A

a number and a unit

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3
Q

how is uncertainty recorded in a measurement?

A

sig figs–all the certain figures plus the first uncertain one

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4
Q

hypothesis

A

one or more assumptions put forth to explain the observed behavior of nature

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5
Q

theory

A

a set of assumptions put forth to explain some aspect of the observed behavior of matter

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6
Q

model

A

a set of assumptions put forth to explain the observed behavior of matter (in chemistry, usu involve assumptions about the behavior about individual atoms or molecules)

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7
Q

natural law

A

a statement that expresses generally observed behavior

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8
Q

law of conservation of mass

A

mass is neither created or destroyed

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9
Q

law of conservation of energy

A

energy is neither created or destroyed

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10
Q

law of definite proportion

A

a given compound always contains exactly the same proportion of elements by mass

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11
Q

law of multiple proportions

A

when two elements form a series of ompounds, the ratios of the masses of the second element that combine with one g of the first element can always be reduced to small whole numbers

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12
Q

What are the 4 components of Dalton’s Theory of Atoms?

A

all elements are composed of atomons
all atoms of a given element are identical
chemical compounds are formed when atoms combine
atoms are not changed in chemical reactions, but the way they are bound together changes

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13
Q

atomic mass (atomic weight)

A

the weighted average mass of the atoms in a naturally occurring element (Dalton, first to make table of atomic masses)

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14
Q

Avogadro’s hypothesis

A

equal volume of gasses at same temp and pressure have an equal number of atoms

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15
Q

cathode-ray tubes

A

the “rays” emanating rom the negative electrode (cathode) in a partially evacuated tube; a stream of electrons

16
Q

electrons

A

a negatively charged particle that moves around the nucleus of the atom, mass is 1/1840 of a proton

17
Q

radioactivity

A

the spontaneous decomposition of a nucleus to form a different nucleus

18
Q

nuclear atom

A

an atom having a dense center of positive charge (the nucleus) with electrons moving around the outside

19
Q

nucleus

A

the small, dense center of positive charge in an atom

20
Q

proton

A

a positively charged particle in an atomic nucleus

21
Q

neutron

A

a particle in the atomic nucleus with mass virtually equal to the proton’s but with no charge

22
Q

isotopes

A

atoms of the same element (the same # of protons) with different numbers of neutrons. They have identical atomic numbers but different mass numbers

23
Q

atomic number

A

the number of protons in the nucleus of an atom

24
Q

mass number

A

the total number of protons and neutrons in the atomic nucleus of an atom

25
Q

energy

A

the capacity to do work or to cause heat flow

26
Q

work

A

force acting over a distance

27
Q

potential energy

A

energy due to position or composition

28
Q

kinetic energy

A

1/2mv^2 energy due to the motion of an object; dependent on the mass of the object and the square of its velocity

29
Q

mole

A

(mol) the number equal to the number of carbon atoms in exactly 12 grams of pure ^12C: Avogadro’s number. One mole represent 6.022 x 10^23 units

30
Q

The Thompson model of the atom

A

the “plum pudding model”; used the cathode-ray tubes to determine that all atoms had electrons and hypothesized that the electrons were embedded randomly in a diffuse cloud of positive charge like raisins in a plum pudding

31
Q

Millikan experiment

A

using charged oil drops and voltage, Millikan was able to determine the magnitude of the electron charge

32
Q

Rutherford experiments

A

by using alpha particles, was able to determine that atoms must have a concentrated positive charge that contains most of the atoms mass

33
Q

the nuclear model

A

the model of the atom that assumes the nucleus contains protons and neutrons and a cloud of electrons surrounding it

68
Q

mole

A

a unit of measurement that represents 6.022x10^23 molecules, Avogadro’s number

69
Q

what is the structure of the atom

A

a small, dense nucleus containing protons and neutrons

electrons that reside outside the nucleus in the relatively large remaining atomic volume