Chapter 1 Flashcards

1
Q

What is petroleum

A

a complex mixture of hydrogen and carbon molecules

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2
Q

What is the simplest hydrocarbon

A

Methane

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3
Q

Hyrdocarbon molecules join together to form what

A

chains

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4
Q

Chains of less than five carbons exist as what

A

gases

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5
Q

Chains of five and twenty exist as what

A

liquids

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6
Q

Chains of over twenty exist as what

A

solids

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7
Q

Hydrocarbon molecules can form into chains of different shapes. This will

A

give substances with the same carbon count different characteristics.

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8
Q

What is volatility

A

tendency of a substance to evaporate at normal temperatures.

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9
Q

It is the ________ given off from a substance that burns, not the substance
itself

A

Vapour

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10
Q

When is vapour given off

A

evaporation process

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11
Q

When evaporation equals condensation….

A

Saturation conditions exist

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12
Q

The pressure exerted when saturation occurs is the _________. _________. ________ (SVP) and this is related to temperature

A

Saturated vapour pressure

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13
Q

If SVP equals atmospheric pressure (approx 1 bar) then…..

A

the liquid will boil

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14
Q

Evaporation takes place from the liquid surface, boiling occurs from…..

A

within the liquid

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15
Q

Volatile substances evaporate…

A

rapidly

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16
Q

Non-volatile substances evaporate

A

slowly

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17
Q

Evaporation is affected by
x 4

A

Evaporation is affected by:
1. Temperature
2. Surface Area
3. Liquid to vapour ratio
4. Turbulence

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18
Q

What does TVP mean

A

True Vapour Pressure

19
Q

What is TVP

A

is the highest pressure possible but is difficult to calculate

20
Q

What does RVP stand for

A

Reid Vapour Pressure

21
Q

What does RVP do

A

is a useful test for comparing the volatility of
different products but does not give an indication of the likely vapour generation within a cargo tank

22
Q

Hydrocarbon vapour is usually denser than…

23
Q

What is flashpoint

A

is the lowest temperature at which a substance gives off enough vapour to briefly ignite when an external source of ignition is applied

24
Q

What is flashpoint a measure of

A

is a measure of a substances flammability

25
What does flashpoint dictate
dictates when a liquid is becoming flammable
26
Tanker cargoes are classified as volatile or non-volatile according to their....
flashpoint
27
If the flashpoint is below 60oC then
the substance is volatile
28
If the flashpoint is 60oC or above
the substance is non-volatile
29
What does AIT stand for
Auto Ignition Temp
30
What is AIT
is the temperature at which a substance will ignite without the application of an external ignition source
31
There is no direct correlation between flashpoint and.....
auto ignition temp
32
* Three things are required for a fire to occur; fuel, oxygen and heat, (source of ignition) * The combination of these must be in the correct proportion to create a fire:
* Oxygen: 11 to 21% by volume * Fuel (petroleum gas): 1 – 10% by volume * Sufficient heat energy to ignite a flammable mixture
33
What does LFL stand for
Lower flammable limit
34
What is LFL
is the lowest concentration of hydrocarbon gas in air to support combustion
35
What does UFL stand for
Upper flammable limit
36
What is UFL
is the highest concentration of hydrocarbon gas in air to support combustion
37
The range between the LFL and the UFL is known as the
Flammable range
38
Area above the UFL is termed
Too rich
39
Area below the LFL is termed
Too lean
40
Region belowe 11% oxygen is termed
inert
41
Toxic means
Poisonous
42
3 main routes of entry for toxic substances
1. ingestion 2. inhalation 3. through the skin
43
What is the main problem of cargo vapour
inhalation
44
* Inhalation of cargo vapour is the main problem * Poisons either act in the short term (_____) or long term (_____) * Petroleum may contain hydrogen ________ (acute) or ________ (chronic)
acute chronic sulphide benzene