Chapter 1 Flashcards

1
Q

What is condensation?

A

A chemical process by which 2 molecules are joined together to make a larger, more complex molecule, with the loss of water.

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2
Q

What happens to entropy during a condensation reaction?

A

There is a loss of entropy

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3
Q

What is hydrolysis?

A

a larger molecule forms two (or more) smaller molecules and water is consumed as a reactant
(“hydro” = water and “lysis” = break) involves adding water to one large molecule to break it into multiple smaller molecules

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4
Q

What happens to entropy during a hydrolysis reaction?

A

Hydrolysis increases entropy or “disorder” because it breaks one molecule into two.

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5
Q

Alkane

A
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6
Q

Alkene

A
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7
Q

Alkyne

A
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8
Q

Arene

A
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9
Q

Haloalkane

A
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10
Q

Alcohol

A
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11
Q

Aldehyde

A
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12
Q

Ketone

A
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13
Q

Carboxylic Acid

A
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14
Q

Acid Anhydride

A
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15
Q

Ester

A
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16
Q

Ether

A
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17
Q

Primary, Secondary, and Tertiary Amine

A
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18
Q

Amide

19
Q

Nitrate

20
Q

Nitrite

21
Q

Nitrile

22
Q

Imine

23
Q

Imide

24
Q

Thiol

25
Sulfide
26
Disulfide
27
What is Endosymbiosis?
a type of symbiosis in which one organism lives inside the other, the two typically behaving as a single organism
28
What is stereochemistry?
The arrangement of the molecule's constituent atoms in 3 dimensional space
29
What are stereoisomers?
Molecules that share the same chemical bonds but have different configurations
30
What is stereospecific?
Interactions between biomolecules require specific configurations
31
How do geometric isomers and cis isomers differ?
Differ in the arrangement of their substituent groups with respect to the nonrotating double bond
32
What are two types of stereoisomers?
Enantiomers (mirror image) and diastereomers (non-mirror images)
33
What type of chiral compound goes in the clockwise direction?
R and in our class, D goes with R
34
What type of chiral compound goes in the counterclockwise direction?
S and in our class, L goes with S
35
What is a chiral center?
An atom that has four different types of groups bonded to it
36
What is the first law of thermodynamics?
In any physical or chemical change, the total amount of energy in the universe remains constant, although the form of the energy may change.
37
What is the second law of thermodynamics?
the total entropy (s) or disorder of the universe is continually increasing
38
What is an endergonic reaction in thermodynamics?
Work done raising objects. Energy is absorbed from the surroundings
39
What is an exergonic reaction in thermodynamics?
Loss of potential energy of position.
40
What do enzymes do in biochemical reactions?
Lower the activation barrier
41
When are Keq reactions at equilibrium?
When ΔG=0 and Keq=1
42
When are Keq reactions exothermic/exergonic and spontaneous?
When ΔG is less than 0 and Keq is bigger than 1
43
When are Keq reactions endothermic/endergonic and nonspontaneous?
When ΔG is bigger than 0 and Keq is less than 1
44
What is enthalpy and entropy?
Enthalpy is the energy contained within chemical bonds (ΔH) and entropy is how disordered things are (ΔS)