chap4, form 5 Flashcards

1
Q

definition of polymer

A

A long chain of molecules consisting of monomers.

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2
Q

2 source of polymer

A

natural polymer

synthetic polymer

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3
Q

5 example of natural polymer

A

starch, carbohydrate, protein, fats, natural rubber

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4
Q

4 example of synthetic polymer

A

terylene, polystyrene, polyethene, nylon

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5
Q

monomer of starch

A

glucose

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6
Q

monomer of protein

A

amino acid

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7
Q

monomer of fats

A

glycerol and fatty acids

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8
Q

monomer of natural rubber

A

isoprene

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9
Q

what are 3 types of polymer

A

thermoplastic
thermosetting
elastomer

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10
Q

definition of thermoplastic polymer

A

Can be repeatedly remoulded by heating, and recycled

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11
Q

definition of thermosetting polymer

A

Cannot be remoulded after heating

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12
Q

definition of elastomer polymer

A

Can be stretched, return to original shape (elastic)

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13
Q

properties of thermoplastic polymer

A

When heated: melt

When cooled: solidify

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14
Q

properties of thermosetting polymer

A

Disintegrate or burn when heated, x recyclable

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15
Q

properties of elastomer polymer

A

Has high elasticity properties

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16
Q

3 example of thermoplastic polymer

A

Polyethene, PVC, nylon

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17
Q

2 example of thermoplastic polymer

A

Melamine, bakelite

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18
Q

example of elastomer polymer

A

Polyurethane, (SBR) Styrene-butadiene rubber

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19
Q

what are the 2 types of polymerisation reaction?

A

addition polymerisation

condensation polymerisation

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20
Q

definition of addition polymerisation?

A

add or break double bonding

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21
Q

addition polymerisation produces polymer ending with ___

A

-ene

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22
Q

characteristic of polyethene

A

durable & strong

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23
Q

use of polyethene

A

plastic bags, bottle, packaging

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24
Q

characteristic of polypropene

A

durable

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25
use of polypropene
toys, textile, medical & laboratory apparatus
26
characteristic of polyvinyl chloride (PVC)
strong & hard
27
use of polyvinyl chloride (PVC)
Water pipes and electrical insulators
28
characteristic of polystyrene
light & heat insulator
29
use of polystyrene
heat insulator, food packaging
30
how many types of condensation polymerisation are there?
2
31
what are the 2 types of condensation polymerisation are there?
form terylene | form nylon
32
condensation polymerisation forms what products?
polymer + water/hydrogen chloride
33
in formation of terylene, what happens to ethanol & carboxylic acid and how is water formed as a byproduct
ethanol loses one H atom carboxylic acid loses hydroxyl the H and OH combine to form H2O
34
in formation of terylene, what kind of bond is formed?
ester bond
35
in formation of nylon, what happens to amine & carboxylic acid and what is formed as a byproduct?
amine loses one H atom carboxylic acid loses one Cl atom H and Cl combine to form HCl
36
in formation of nylon, what bonding is formed?
a dipeptide/amide bonding formed
37
synthetic polymers are ____ and ____, relatively ____, can withstand ____ and __1__ __2__, can withstand ___, ___-_____, easily ____
``` light and strong cheap corrosion chemical reaction water non-flammable mould to shape ```
38
most polymers are not ____, the __1__ __2__ of plastics gives rise to ____ and ____ gases like _____ , ____ and _____ that can cause ___ burning of plastics can also produce ____ that worsens the _____ ___1___ __2__ can cause __ of marine creature when _____ enter their ____ ____ drains can cause ____
biodegradable poisonous, acidic gases carbon monoxide, hydrogen chloride and hydrogen cyanide acid rain carbon dioxide, greenhouse effect Marine pollution, death microplastic, food chain Block , flash floods
39
r____ polymers : through ___, plastics ____ by ___ them without ___ at ___. the products of this process are then ____ into _____ i_____ b___ polymers: ___ polymers with ____ that can be ____ by ____ (to become _____) or through ____ (______)
Recycling, pyrolysis, decompose, heating, oxygen, 700°C, recycled, new products. Inventing, biodegradable, Mix, additives, decomposed, bacteria (biodegradable) (photodegradable).
40
IUPAC name of isoprene
2, methylbut-1,3-diene
41
polyisoprene is surrounded with ___
negatively charged particles
42
how does latex remain as liquid?
the negatively charged particles repel each other
43
use of rubber (latex) | clue they start w/ rubber
rubber gloves. rubber boots, tires, soles of shoes
44
rubber is a w___ s___ at ___
white, solid, 25 C
45
rubber is ____ and can be ____ and ____ to original ___ when ____
elastic, stretched, return, shape, released
46
at ___ temperature, rubber turns ___ and ___
high, soft, sticky
47
rubber cannot ____ e____
conduct electricity
48
rubber is easily ____ because the ___ in air react with _____ between ___ atoms
oxidised, oxygen gas, double bond, carbon
49
rubber reacts easily with ___, ___, ____
acids, alkalis, organic solvents
50
rubber is ____ | clue: we are bulletproof
waterproof
51
what are the 2 ways for later to coagulate?
natural | artificial
52
how is latex coagulated naturally? | simple je yah explain lagi
bacteria from air enters rubber and secretes lactic acid containing H+ ions
53
how is latex coagulated artificially? | simple je yah explain lagi
dilute acid containing H+ ions
54
describe process of coagulation of latex
the lactic acid/dilute acid containing H+ ion react with negatively charged particles which will neutralise the rubber particles. then the rubber particles collide against each other, breaking the protein membrane surrounding polyisoprene. Polyisoprene will clump together, changing the state of matter from liquid to solid.
55
latex is more valuable when given in ___
liquid form
56
to prevent coagulation of latex. what is added
NH4OH (ammonium hydroxide) or aqueous ammonia as it contains OH- ion
57
how does NH4OH or aqueous ammonia prevent coagulation of latex?
it neutralises the H+ ion produced by bacteria as it contains OH- ions. the protein membrane remains negatively charged and continue to repel each other
58
ionic equation of NH4OH
NH4OH --> NH4+ + OH-
59
neutralisation eq that occurs
OH- + H+ --> H2O
60
Why is strong acid not used in coagulation of latex?
that would cause a sudden drop in pH, leading to irregular coagulation of the latex particles.
61
what is the best quality of latex ?
sheet rubber
62
what is the 2nd best quality of latex?
block rubber
63
what is the lowest quality of latex?
clump rubber
64
why do rubber tappers have to collect latex before sunrise (7 am)? (relate to rate of reaction)
As the sun rises, the surrounding temperature increases. Increase in temperature will increase the rate of reaction. Increase in reaction because higher collision frequency and particles vibrate rapidly. rubber particles collide frequently with H+ ion of bacteria.
65
definition of vulcanisation of rubber
a process of producing rubber that is more elastic and with better quality through the production of cross-links between polymer chains.
66
what is vulcanisation of rubber
sulphur
67
3 characteristics of vulcanised rubber
hard, non-sticky, more elastic
68
vulcanised rubber used in daily life as
car tyre
69
how is rubber vulcanised?
Adding sulphur compound into latex - forming sulphur link - maintain elasticity of rubber