Chap 16 Flashcards

1
Q

Chemical kinetics

A

Area of chemistry concerned with speed, or rate, at which chemical reaction occurs

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2
Q

Reaction rate

A

Change of a reactant or product per unit time

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3
Q

Reaction rate law

A

an expression showing the relationship of the reaction rate to the concentrations of each reactant.

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4
Q

Initial rate

A

Rate at beginning of the reaction

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5
Q

Specific rate constant

A

Symbol k, proportionality constant relating the rate of the reaction to the concentrations of reactants.

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6
Q

Elementary reaction

A

One that occurs in a single step

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7
Q

Unimolecular reaction

A

Reaction because it only has one reactant molecule (A to products)

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8
Q

Bimolecular reaction

A

Has 2 reactant molecules (A + B to products)

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9
Q

Trimolecular reaction

A

3 molecules reaction (A+B+C to products )

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10
Q

Reaction order

A

relationship between the concentrations of species and the rate of a reaction.

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11
Q

First order reaction

A

The reaction rate is directly proportional to the concentration of only one reactant

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12
Q

Overall reaction order

A

Is the sum of the orders with respect to each reactant in the rate law

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13
Q

Concentration

A

Defined as a quantitative measure of the amount of solute dissolved in a given amount of solvent

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14
Q

Catalyst

A

Substance that increases the rate of a chemical reaction without being consumed in the reaction

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15
Q

Enzymes

A

Protein molecules that act as catalysts

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16
Q

Biochemical reactions

A

Chemical reaction taking place in living matter

17
Q

Homogeneous catalyst

A

Is a catalyst that is in the same phase as the reactants

18
Q

Heterogeneous catalyst

A

Catalyst and the reactants it is working on are not the same phase

19
Q

Inhabitants

A

Compounds that slow down or inhibit chemical reactions

20
Q

Collision theory, collision model

A

States that atoms, ions, and molecules must collide with each other to react

21
Q

Activated complex, transition state

A

Which is an intermediate particle made up of joined reactants

22
Q

Intermediate particle

A

Particle that appears in the mechanism of the reaction, ie in the elementary steps, but not in the overall balanced equation

23
Q

Complex reactions

A

One that consists of 2 or more elementary steps

24
Q

Reaction mechanism

A

Series of elementary steps that lead to products formation

25
Q

Rate determine step rds

A

Slowest step in the sequence of steps leading to product formation