Chap 16 Flashcards
Chemical kinetics
Area of chemistry concerned with speed, or rate, at which chemical reaction occurs
Reaction rate
Change of a reactant or product per unit time
Reaction rate law
an expression showing the relationship of the reaction rate to the concentrations of each reactant.
Initial rate
Rate at beginning of the reaction
Specific rate constant
Symbol k, proportionality constant relating the rate of the reaction to the concentrations of reactants.
Elementary reaction
One that occurs in a single step
Unimolecular reaction
Reaction because it only has one reactant molecule (A to products)
Bimolecular reaction
Has 2 reactant molecules (A + B to products)
Trimolecular reaction
3 molecules reaction (A+B+C to products )
Reaction order
relationship between the concentrations of species and the rate of a reaction.
First order reaction
The reaction rate is directly proportional to the concentration of only one reactant
Overall reaction order
Is the sum of the orders with respect to each reactant in the rate law
Concentration
Defined as a quantitative measure of the amount of solute dissolved in a given amount of solvent
Catalyst
Substance that increases the rate of a chemical reaction without being consumed in the reaction
Enzymes
Protein molecules that act as catalysts
Biochemical reactions
Chemical reaction taking place in living matter
Homogeneous catalyst
Is a catalyst that is in the same phase as the reactants
Heterogeneous catalyst
Catalyst and the reactants it is working on are not the same phase
Inhabitants
Compounds that slow down or inhibit chemical reactions
Collision theory, collision model
States that atoms, ions, and molecules must collide with each other to react
Activated complex, transition state
Which is an intermediate particle made up of joined reactants
Intermediate particle
Particle that appears in the mechanism of the reaction, ie in the elementary steps, but not in the overall balanced equation
Complex reactions
One that consists of 2 or more elementary steps
Reaction mechanism
Series of elementary steps that lead to products formation