Ch9 Crude oils and fuels Flashcards

1
Q

Crude oil contents

A

mixture of hydrocarbons with lots of different boiling points

petrol
naphtha
kerosene
diesel oil
heavy fuel oil 
liquefied petroleum gases
bitumen
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2
Q

Formation of crude oil

A

ancient biomass(plankton) buried under mud

layers of rock are laid down on top which creates high pressure, lack of oxygen and high temperature

conditions creates crude oil

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3
Q

fractions

A

different substances with similair boiling points

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4
Q

General formula for alkanes

A

CnH2n+2

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5
Q

Order for hydrocarbons

A
meth-
eth-
prop-
but-
pent-
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6
Q

Hydrocarbons

A

a compound that contains only hydrogen and carbon atoms

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7
Q

hydrocarbon properties

A

short chain long chain
lower bp < higher bp
higher volatility > lower volatility
low runny viscosity < high thick viscosity
high flammability > low flammability

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8
Q

saturated hydrocarbons

A

alkanes

all carbon bonds are single and covalent

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9
Q

unsaturated hydrocarbons

A

alkenes

contains at least one double bond between carbon atoms

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10
Q

Fractional distillation of crude oil

A

Crude oil is heated(vaporised) and fed into the bottom of the fractionating column
Column is kept hot at the bottom and cooler at the top
Gases move up the column, and the hydrocarbons condense when they reach the boiling point
They are then collected off the side in their separate factions

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11
Q

Complete combustion of a hydrocarbon

A

Produces CO2 and H2O
Carbon and hydrogen oxidise completely when they burn in plenty of air
Transfers lots of energy to the surroundings

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12
Q

Incomplete combustion of a hydrocarbon

A

Carbon and Hydrogen don’t oxidise completely because there is not enough oxygen
Produces water and carbon/carbon monoxide

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13
Q

Why crack hydrocarbons

A

heavier fractions from fractional distillation aren’t useful because

  1. high boiling point
  2. difficult to vaporise
  3. don’t burn easily(poor fuels)
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14
Q

How to crack a hydrocarbon

A
  1. Place hydrocarbon into a steel vessel(cracker)
  2. heated to vaporise the hydrocarbon
  3. a. pass over a hot catalyst
    b. mixed with steam and heated to high temperature
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15
Q

cracking hydrocarbons

A

thermal decomposition reactions

creates alkenes and smaller alkanes

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16
Q

Positive test for an unsaturated hydrocarbon

A

Mix hydrocarbon with orange bromine water

It will turn colourless

17
Q

Homologous series

A

examples are alkanes or alkenes
compounds have similair properties and structures
compounds have same functional group