Ch9 Crude oils and fuels Flashcards
Crude oil contents
mixture of hydrocarbons with lots of different boiling points
petrol naphtha kerosene diesel oil heavy fuel oil liquefied petroleum gases bitumen
Formation of crude oil
ancient biomass(plankton) buried under mud
layers of rock are laid down on top which creates high pressure, lack of oxygen and high temperature
conditions creates crude oil
fractions
different substances with similair boiling points
General formula for alkanes
CnH2n+2
Order for hydrocarbons
meth- eth- prop- but- pent-
Hydrocarbons
a compound that contains only hydrogen and carbon atoms
hydrocarbon properties
short chain long chain
lower bp < higher bp
higher volatility > lower volatility
low runny viscosity < high thick viscosity
high flammability > low flammability
saturated hydrocarbons
alkanes
all carbon bonds are single and covalent
unsaturated hydrocarbons
alkenes
contains at least one double bond between carbon atoms
Fractional distillation of crude oil
Crude oil is heated(vaporised) and fed into the bottom of the fractionating column
Column is kept hot at the bottom and cooler at the top
Gases move up the column, and the hydrocarbons condense when they reach the boiling point
They are then collected off the side in their separate factions
Complete combustion of a hydrocarbon
Produces CO2 and H2O
Carbon and hydrogen oxidise completely when they burn in plenty of air
Transfers lots of energy to the surroundings
Incomplete combustion of a hydrocarbon
Carbon and Hydrogen don’t oxidise completely because there is not enough oxygen
Produces water and carbon/carbon monoxide
Why crack hydrocarbons
heavier fractions from fractional distillation aren’t useful because
- high boiling point
- difficult to vaporise
- don’t burn easily(poor fuels)
How to crack a hydrocarbon
- Place hydrocarbon into a steel vessel(cracker)
- heated to vaporise the hydrocarbon
- a. pass over a hot catalyst
b. mixed with steam and heated to high temperature
cracking hydrocarbons
thermal decomposition reactions
creates alkenes and smaller alkanes