Ch4 Chemical calculations Flashcards
Avogadro constant
6.02 x 10^23 atoms in one mole
mole formula
mass/ (Mr)
mass formula
mole x Mr
Mr
relative formula mass
sum of mass numbers of elements within
percentage yield formula
(actual mass/ theoretical mass) x 100%
Factors affecting percentage yield
- reaction may be reversible
- may produce unexpected or unwanted products in alternative reactions
- some products may be lost during separation
- reactants may no be pure
atom economy
measure of the amount of starting materials that end up as useful products
atom economy formula
(Mr of desired product/ Mr of all reactants) x 100%
concentration of a solution g/dcm^3
(mass of solute/ volume of solution cm^3) x 1000
mass of solute/ volume of solution dm^3
concentration of a solution mol/dcm^3
moles in solute/ volume of solution dm^3
(mass/Mr) / volume of solution dm^3
Volume of a gas dm^3
mole of gas x 24 dm^3
(Mass/Mr) x 24 dm^3
1dm^3
1000cm^3
mole of gas
vol of gas/ 24dm^3 or 24,000^3
volume of one mole of gas
24dm^3 at room temperature and pressure
Titration method
- Use the pipette and pipette filler to add 25 cm3 of alkali to a clean conical flask.
- Add a few drops of indicator(pink phenolphthalein) and put the conical flask on a white tile.
- Fill the burette with acid and note the starting volume.
- Slowly add the acid from the burette to the alkali in the conical flask, swirling to mix.
- Stop adding the acid when the indicator phenolphthalein changes to colourless. Note the final volume reading.
- Calculate the titre by finding the difference between the end and starting volume
- Repeat steps 1 to 5 until you get concordant titres(within 0.1cm^3 of each other)
- Calculate the mean titre