Ch28 Organic Synthesis A2 Flashcards
Describe the synthesis of an Alkane from an Alkene (include equation, reagents, type of reaction)
Describe the synthesis of a Haloalkane from an Alkane (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of a Nitrile from an Haloalkane (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of an Amine from a Nitrile (include equation, reagents, type of reaction)
Describe the synthesis of a Haloalkane from an Alkene (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of an Amine from a Haloalkane (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of an Alkene from an Alcohol (include equation, reagents, type of reaction)
Describe the synthesis of an Alcohol from an Alkene (include equation, reagents, type of reaction)
Describe the synthesis of an Alcohol from a Haloalkane (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of a Haloalkane from an Alcohol (include equation, reagents, type of reaction)
Describe the synthesis of a Ketone from a 2º Alcohol (include equation, reagents, type of reaction)
Describe the synthesis of a 2º Alcohol from a Ketone (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of a Hydroxyamine from a Hydroxynitrile (include equation, reagents, type of reaction)
Describe the synthesis of an Aldehyde from an Alcohol (include equation, reagents, type of reaction)
Describe the synthesis of a 1º Alcohol from an Aldehyde (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of an Ester from an Alcohol (include equation, reagents, type of reaction)
Describe the synthesis of a Carboxylic Acid from a 1º Alcohol (include equation, reagents, type of reaction)
Describe the synthesis of a Hydroxynitrile from a Ketone (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of a Hydroxynitrile from an Aldehyde (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of a Carboxylic Acid from an Aldehyde (include equation, reagents, type of reaction)
Describe the synthesis of a Carboxylic Acid from a Nitrile (include equation, reagents, type of reaction)
Describe the synthesis of a Carboxylic Acid from a Hydroxynitrile (include equation, reagents, type of reaction)
Describe the synthesis of an Ester from a Carboxylic Acid (include equation, reagents, type of reaction)
Describe the synthesis of a Carboxylic Acid from an Ester (include equation, reagents, type of reaction)
Describe the synthesis of a Sodium Carboxylate from an Ester (include equation, reagents, type of reaction)
Describe the synthesis of an Ester from an Acyl Chloride (include equation, reagents, type of reaction)
Describe the synthesis of a Carboxylic Acid from an Acyl Chloride (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of an Acyl Chloride from a Carboxylic Acid (include equation, reagents, type of reaction)
Describe the synthesis of a 1º Amide from an Acyl Chloride (include equation, reagents, type of reaction)
Describe the synthesis of a 2º Amide from an Acyl Chloride (include equation, reagents, type of reaction)
Describe the synthesis of Methyl Benzene from Benzene (include equation, reagents, type of reaction)
Describe the synthesis of Nitrobenzene from Benzene (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of Bromobenzene from Benzene (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of Chlorobenzene from Benzene (include equation, reagents, type of reaction, mechanism)
Describe the synthesis of Phenylethanone from Benzene (include equation, reagents, type of reaction)
Describe the synthesis of Phenylamine from Nitrobenzene (include equation, reagents, type of reaction)
Describe the synthesis of 2,4,6,-tribromophenylamine from Phenylamine (include equation, reagents, type of reaction)
Describe the synthesis of Phenylethanol from Phenylethanone (include equation, reagents, type of reaction)
Describe the synthesis of a 2-nitrophenol/4-nitrophenol from a Phenol (include equation, reagents, type of reaction)
Describe the synthesis of a 2,4,6-tribromophenol from a Phenol (include equation, reagents, type of reaction)
Describe the synthesis of a Sodium Phenoxide from Phenol (include equation, reagents, type of reaction)
How can a nitrile group be added to organic compounds using haloalkanes? Talk about reagents, type of reaction, and the general equation.
How can a nitrile group be added to organic compounds using aldehydes/ketones? Talk about reagents, type of reaction, general equation.
How can a nitrile compound be reduced?
Explain the hydrolysis of Nitriles, using reagents and the general equation:
What are the methods of increasing C-C bonds in benzene? Name the process, the reagents, and the general equation.
Explain how Grignard Reagents work; talk about what organometallic compounds are, their uses in organic chemistry, the reagents used and the steps involved.
Organometallic compound = C-Metal bond, useful for increasing length of carbon chain, usually Mg or Li used.
Steps:
1. Organometallic compound provides source of type of nucleophile called ‘carbanion’, which contains carbon with delta negative charge.
2. Carbanion reacts w/ positively charged carbon atom/chain to form new C-C bond.
Explain filtration under reduced pressure as a method of preparation of organic solid:
Explain the method of recrystallisation as a method of purifying impure organic solids:
Describe the method of melting point determination:
