Ch10 Nitrogen compounds Flashcards
1
Q
Naming amine
A
- thylamine
2
Q
Primary amine
A
RNH2
3
Q
Secondary amine
A
RRNH
4
Q
Tertiary amine
A
RRRN
5
Q
Hydrogen bonds
A
between lone pair on N and delta + on H in adjacent molecule
6
Q
Haloalkane + ammonia
A
RCl + NH3 -> RNH2 + HCl
Nucleophilic substitution
7
Q
Reduction of nitriles
A
RCN + 4[H] -> RCH2NH2
Catalyst LiAlH4
8
Q
Alcohol + ammonia
A
ROH + NH3 -> RNH2 + H2O
9
Q
overall forming phenylamine
A
nitrobenzene + 6[H] -> phenylamine
reflux SN/conc HCl
10
Q
amine + acid
A
salt + water
11
Q
Amide formula
A
R- CONH2
12
Q
Hydrolysis of amide with acid
A
amide -> carboxylic acid + RNH3
heat with HCl/H2O
13
Q
Hydrolysis of amide with base
A
amid ->
14
Q
chirality of amino acids
A
asymmetrical molecule that are non-superimposable mirror images
carbon is attached to 4 different R groups
