Ch. 9-12 Flashcards

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1
Q

Work done on a gas

A

W=-P△V

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2
Q

Change in Internal Energy

A

△U= Q + W

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3
Q

Change in Internal Energy of an Ideal Gas

A

△U= n Cv △T

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4
Q

Isobaric Process (△U, Q, and W)

A

△U= nCv△T
Q= nCp△T
W=-P△V

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5
Q

Adiabatic Process

A
△U= nCv△T
Q= 0
W= △U
Constant =  (PV)^gamma
Gamma= Cp/Cv
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6
Q

Isovolumetric Process

A
△U= nCv△T
Q= △U
W= 0
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7
Q

Isothermal Process

A
△U= 0
Q= -W
W= -nRTln(Vf/Vi)
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8
Q

General Thermal Processes

A
△U= nCv△T
Q= △U-W
W= PV (Area)
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9
Q

Degree of Freedom

A

each different way a gas molecule can store energy; contributes 1/2R to the molar specific heat capacity; monoatomic Cv= 3/2R; diatomic Cv= 5/2R

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10
Q

Heat capacity at Constant Pressure

A

Cp= Cv + R

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11
Q

Work Done by a Heat Engine

A

Weng = l Qh l -l Qc l

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12
Q

Thermal Efficiency of a Heat Engine

A

e= 1 - [Qc]/[Qh]

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13
Q

Coefficient of Performance

A

COP = Q/W

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14
Q

Carnot Cycle Efficiency

A

e (c) = 1 - Tc/Th

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15
Q

Entropy

A
△S= Qr/T
Qr= heat flow as the system changes from one state to another
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16
Q

Energy required to change Temperature

A

Q=mc△T

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17
Q

Energy required to change the phase

A

Q= +/-mL

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18
Q

Rate of Energy Transfer

A
P= kA (Th-Tc)/L
k= thermal conductivity
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19
Q

Rate of Radiation Emission

A

P (net) = sigmaAe(T^4 - Ti^4)

20
Q

Ideal Gas Law

A

PV=nRT

21
Q

Pressure of N molecules of an Ideal Gas

A

P = 2/3 (N/V) (1/2mv^2)

22
Q

Linear Expansion

A

△L = ⍺Li△T

23
Q

Area Expansion

A

△A = gammaAi△T

24
Q

Volume Expansion

A

△V = ℬVi△T

25
Q

Relationship between Celsius and Kelvin

A

Tc = T - 273.15

26
Q

Relationship between Fahrenheit and Celcius

A

Tf = 9/5Tc + 32

27
Q

Density

A

⍴ = M/V

28
Q

Pressure in a fluid

A

P = F/A

29
Q

Stress

A

stress = elastic modulus x strain

30
Q

Young’s Modulus

A

F/A=Yi△L/Li

31
Q

Pressure when Barometer is at a certain height

A

P= ⍴gh

32
Q

Buoyancy

A

⍴Vg

33
Q

Equation of continuity

A

A1V1=A2V2

34
Q

Variation of Pressure with Depth

A

P2=P1 + ⍴g (y1-y2)

35
Q

Pascal’s Principle

A

F1/A1=F2/A2

36
Q

Buoyancy when Object is Submerged

A

B=⍴(fluid)V(obj)g
w=mg=⍴(obj)V(obj)g
Net Force=B-w=(⍴(fluid)-⍴(obj)) V(obj)g

37
Q

Buoyancy when Object is Floating

A

w=mg=⍴objVobjg
⍴fluidVfluidg=⍴objVobjg
use m=⍴waterAh

38
Q

Surface Tension

A

gamma = F/L

39
Q

Capillary Action

A

h=2(gamma)/⍴gr (cosAngle)

40
Q

Viscous Fluid Flow

A
F = n (Av/d)
n= coefficient of viscosity
41
Q

Rate of Viscous Flow

A

[piR^4 (P1-P2)]/8nL=Rate
n = coefficient of viscosity
R= radius

42
Q

Transport Phenomena (diffusion rate)

A

Mass/Time
=DA((C2-C1)/L)
D= constant of proportionality
C2-C1/L = concentration gradient

43
Q

Stoke’s Law (motion through a viscous medium)

A
F = 6 pi n r v
n= viscosity
v= speed
r= radius
44
Q

Force of Gravity through a viscous medium

A

W=⍴gV=⍴g(4/3pi r^3)

45
Q

Buoyant force through a viscous medium

A

B= ⍴(f)gV = ⍴(f)g(4/3 pi r^3)

46
Q

Terminal Speed

A

v(t)= mg/k (1-(⍴(f)/⍴))

47
Q

Centrifuge Motion (Sedimentation Rate)

A

V(t)=(( m⍵^2r)/k)(1-⍴(f)/⍴)