Ch. 6- Gases, Liquids, Solids, and Intermolecular Forces Flashcards

1
Q

melting point

A

the temperature at which a substance changes from the solid to the liquid state

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2
Q

boiling point

A

the temperature at which the pressure of the vapor escaping from a liquid equals the outside pressure

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3
Q

vaporization

A

the process by which a substance changes from the liquid to the gaseous state

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4
Q

condensation

A

the process by which a substance changes from the gaseous state to the liquid state

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5
Q

freezing

A

the reverse of melting; changing from the liquid to the solid state

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6
Q

sublimation

A

conversion of a solid directly to the gaseous state without going through the liquid state

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7
Q

deposition

A

the direct formation of a solid from a gas without passing through the liquid state; reverse of sublimation

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8
Q

dipole-dipole forces

A

the attractive forces that exist among polar covalent molecules

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9
Q

dispersion forces

A

the momentary, usually weak attractive forces between molecules resulting from electron motions that create short-lived dipoles

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10
Q

dispersion forces

A

the momentary, usually weak attractive forces between molecules resulting from electron motions that create short-lived dipoles

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11
Q

where can dispersion forces exist?

A

between ANY two particles that have electrons (whether they’re polar, nonpolar, or ionic)

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12
Q

hydrogen bond

A

a type of intermolecular force in which a hydrogen atom covalently bonded in one molecule is attracted to a nonmetal atom in a neighboring molecule; both the atom to which the hydrogen atom is bonded and the one to which it is attracted are small, highly electronegative atoms, usually N, O, or F

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13
Q

how do we know if dipole-dipole forces exist between molecules?

A

if the molecules are polar, and hydrogen bonding is not possible

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14
Q

how do we know if dispersion forces exist between molecules?

A

if the molecules are nonpolar, because nonpolar molecules can ONLY exhibit dispersion forces, and no other forces

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15
Q

how do we know if hydrogen bonding exists between molecules?

A

if the molecules are polar, and they consist of H covalently bonded to N, O, or F in one molecule, and N, O, or F in a polar bond in a neighboring molecule

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16
Q

how do intermolecular forces range in strength?

A

weakest–>strongest

dispersion forces, dipole-dipole forces, hydrogen bonding

17
Q

kinetic-molecular theory

A

an explanation of the behavior of gases based on the motion and energy of particles; includes 5 basic concepts:

  1. particles of a gas (usually molecules, but atoms in the case of noble gases) are in rapid, constant motion and move in straight lines
  2. the particles of a gas are tiny compared with the distances between them
  3. because the particles of a gas are so far apart, there is very little interaction between them
  4. particles of a gas collide with one another & energy is conserved in these collisions (because energy lost by one particle is gained by the other)
  5. temperature is a measure of the average kinetic energy (energy of motion) of the gas particles
18
Q

Boyle’s Law

A

states that for a given mass of gas at constant temperature, the volume varies inversely with the pressure; PV=k; first gas law created

19
Q

William Thomson

A

Scots-Irish physicist who created an absolute temperature scale known as the Kelvin scale, which has -273.15°

20
Q

Charles’s Law

A

states that for a given mass of gas at constant pressure, the volume varies directly with the absolute temperature; V/T=k

21
Q

Gay-Lussac’s Law

A

states that the pressure of a fixed amount of gas at fixed volume is directly proportional to its temperature in kelvins; P/T=k

22
Q

Avogadro’s Law

A

states that at a fixed temperature and pressure, the volume of a gas is directly proportional to the amount (# of moles) of gas; V/n=k

23
Q

molar volume

A

the volume occupied by 1 mol of a substance (usually a gas) under specified conditions

24
Q

standard temperature and pressure (STP)

A

conditions of 0°C and 1 atm pressure

25
Q

at STP, how much can 1 mol of any gas occupy?

A

22.4L

26
Q

combined gas law

A

the single relationship that incorporates the simple gas laws; PV=kT

27
Q

ideal gas law

A

states that the volume of a gas is proportional to the amount of gas and its Kelvin temperature, and inversely proportional to its pressure; PV=nRT

28
Q

what is “the gas constant”?

A

R = 0.0821 (L x atm)/(mol x K)