Ch. 4 Imperfections in solids Flashcards
Solidification process
crystals nuclei starts appearing, nuclei starts to grow to form crystals or grains
Types of imperfections
point, line, area
Examples of point defects
vacancy atoms, interstitial atoms, substitutional atoms
Example of line defects
Dislocation(line and twist)
Examples of area defects
grain boundaries
EQ for concentration of point defects
Nv/N = exp(-Qv/kT) Nv vacancies per unit ^3, N = atoms per unit ^3, k = Boltzmanns constant
N formula
N = NaP/A (1 mol * density)/atomic mass)
Requirements for subsitutional solid solution
delta 15%, similar electronegativity, same crystal stucture, same valency
Composition percentage formula by weight
C1 = m1/(m1+m2) * 100
Edge dislocations vector
line perpendicular to Burgers vector
Screw dislocations vector
// to burgers vector
Surface Defects
Grain boundaries, Bulk/Volume Defects
Examples of bulk/volume defects
cracks, pores, etc..
How to observe crystal structures
Section cut & grind, polish, etching, microscope
Grain size detetmination
AVG grain diameter = L/NgM (magnification)