Ch 4 - Fire Dynamics Flashcards
Pyrolysis
the chemical decomposition of a solid into a gas by heating
Autoignition
the fuel is heated to the point at which combustion can occur without the need for a flame or spark
Fire triangle
heat, oxygen, fuel
Fire tetrahedron
heat, oxidizer, fuel (reducing agent), chemical chain reaction
Carbon-based fuels
wood, cotton
Hydrocarbon fuels
plastics, synthetic fibers, petroleum products
Vapor density
the density of gases in relation to air
Specific gravity
ratio of density of a given liquid to the density of water
Flash point
minimum temperature at which a liquid gives off sufficient vapors to ignite, but not sustain combustion
Fire point
temperature at which sufficient vapors will begin a sustained combustion reaction
Solubility
the extent to which a substance will mix with water
Miscible
materials that are capable of being mixed in all proportions
Polar solvents
alcohols, mix with water, flammable
Stages of Fire Development
Incipient, Growth, Fully Developed, Decay
Incipient Stage
ignition when three elements of fire triangle come together. Fire is small and contained to fuel of origin
Growth Stage
More of initial fuel becomes involved and will begin to spread to other nearby fuels
Fully Developed Stage
all combustible materials in the compartment are burning at their peak heat release rate based on the available oxygen
Decay Stage
Heat release rate begins to decline as the amount of available fuel or oxygen begins to decrease
Neutral plane
the interface between the stratified layers of hot gas and cool air
Flashover
rapid transition from growth stage to fully developed when all combustible materials and fuel gases in a compartment ignite
Two Biggest Factors Influencing Danger of Structure Fire
1) Fuel load
2) Building construction/integrity
Legacy Construction Benefits
smaller compartments, more compartments, operational windows, air pockets as insulation
Modern Construction Detriments
Open floor plans, high ceilings, lightweight manufactured structural elements, sealed windows, synthetic insulation