Ch 4 Alkanes And Cycloalkanes Flashcards

1
Q

Eth

A

2

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2
Q

Prop

A

3

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3
Q

But

A

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4
Q

Pent

A

5

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5
Q

Hex

A

6

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6
Q

Hept

A

7

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7
Q

Oct

A

8

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8
Q

Non

A

9

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9
Q

Dec

A

10

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10
Q

Undec

A

11

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11
Q

Dodec

A

12

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12
Q

Tridec

A

13

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13
Q

Tertadec

A

14

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14
Q

Pentadec

A

15

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15
Q

Eicos

A

20

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16
Q

Triacont

A

30

17
Q

Tetracont

A

40

18
Q

Pentacont

A

50

19
Q

Hect

A

100

20
Q

Alkyl group

A

An alkane missing one hydrgen

21
Q

Isopropyl

A
22
Q

Sec-

A

The prefix “sec” or “s” is used when the functional group is bonded to a secondary carbon. This prefix is only useful for a four-carbon chain. It is not applicable with a shorter chain, and it is often ambiguous when the chain has five or more carbons.

23
Q

Tert-butyl

A

The prefix “tert” or “t” is used when the functional group is bonded to a tertiary carbon.

24
Q

Branched alkane said are ______in energy then straight chain alkane.

A

Lower in energy(more stable)

25
Q

Conformations

A

A variety of possible three dimensional shape a compound can adopt

26
Q

Dihedral angle or Torsional angle

A

The angle between two planes,where each plane is defined by three atoms, 60 degrees

27
Q

Staggered conformation

A

Two atoms and/or group whose dihedral angle is 60 degrees. Their bonds to the axis of rotation are not aligned. Lowest energy conformation

28
Q

Eclipsed conformation

A

Two atoms and/or groups whose dihedral angle is 0 degrees. Their bonds on the axis of rotation are aligned,highest in energy

29
Q

Degenerate

A

Systems that are equal in energy

30
Q

Torsional strain

A

Strain caused by van der Waals repulsion which can be reduced or eliminated by rotation around a single bond.strain between the eclipsed atoms

31
Q

Anti conformation

A

The conformation with a dihedral angle of 180 degrees

32
Q

Angle strain

A

The increase in energy associated with a bond angle that has deviated from the preferred angle of 109.5 degrees

33
Q

Boat conformations

A

?

34
Q

Cis

A

Two groups are on the same side

35
Q

Trans

A

Two groups are on opposite sides