Ch. 11: Aldéhydes et Cétones Flashcards by who you

Q

Nomenclature

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Q

Nomenclature des aldéhydes

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Q

Nomenclature des Cétones

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Q

Formaldéhyde et Acétone

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Q

Propriétés physico-chimiques

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Q

Double liaison C=O

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Q

Tautomérie

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Q

Tautomérie céto-énol

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Q

Renforcement de l’acidité du H en α :

«1,3-dicarbonyle»

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Q

Réactivité des carbonyles

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Q

Substitution en α en milieu basique

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Q

Addition nucléophile en milieu basique

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Q

(A_N) Réaction supplémentaire:

Déshydratation d’un alcool

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Q

Addition nucléophile en milieu acide

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Q

Réaction d’addition nucléophile avec différents nucléophiles

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Q

Tautomérie imine-énamine

A

Q

Application: protection d’un groupe carbonyle en synthèse

A

Q

Autre A_N: réaction de Grignard (pas en miieu acide)

A

Q

Oxydation des carbonyles

A

Q

Réduction des carbonyles

A

Q

Réduction des carbonyles: mécanisme

A

Q

Préparation des carbonyles

(Friedel-Craft)

A

Q

Préparation des carbonyles

Mécanisme

A

Q

Résumé réactivité des carbonyles

A