Ch 10 - Molecular Shape Flashcards
best lewis structure
minimal formal charge
negative charge on the most EN atom
formal charge
box method
bond order equation
bonding pairs/# atom pairs held together
resonance structure
same placement of atoms, but different placement of bonding and nonbonding electrons
exceptions to octet rule
electron deficient central atom: Be and B
odd electron molecules
expanded octet: period 3+
electron geometry
linear, trigonal planar, tetrahedral, trigonal bipyramidal, octahedral
linear (2)
2 bonding
180
trigonal planar
3 bonding
120
bent (3)
2 bonding, 1 lone
< 120
tetrahedral
4 bonding
109.5
trigonal pyramidal
3 bonding, 1 lone
< 109.5
bent (4)
2 bonding, 2 lone
«109.5
trigonal bipyramidal
5 bonding
axial: 90
equatorial: 120
lone pairs go equatorial since longer bond angle decrease repulsions
seesaw
4 bonding, 1 lone
axial: < 90
equatorial: < 120
T shape
3 bonding, 2 lone
< 90