Ch 10 - Molecular Geometry Flashcards
VSEPR
Valence Shell Electron Pair Repulsion theory.
Electron groups around the central atom will be most stable when they are as far apart from each other as possible.
Linear Geometry
Lined up with 180 degrees between atoms.
Electron Geometry: Linear
Molecular Geometry: Linear
Trigonal Planar Geometry
3 electron groups form a triangle around central.
120 degree bond angles.
Tetrahedral Geometry
4 electron groups around a central. Form a pyramid.
Bond angle 109.5 degrees.
Trigonal Bipyramidal Geometry
5 electron pairs. Form
3 in one plane with 120 degree angles.
2 above and below at 90 degree angles.
Octahedra;
6 groups around central atom.
90 degree angles between all.
Electron geometry: Octahedral
Molecular Geometry: Octahedral
Nonbonded pairs VS bonded pairs
nonbonded pairs are physically bigger and exert more repulsion(shortens bond angles slightly)
Trigonal pyramidal Shape
Electron Geometry: Tetrahedral
Molecular Geometry: Trigonal Pyramidal(1 non bonded pair still exerts force)
Tetrahedral Bent Shape
Electron Geometry: Tetrahedral
Molecular Geometry: Bent
Seasaw Shape
Electron Geometry: Trigonal Bipyramidal
Molecular Geometry: Seasaw
T-Shape
Electron geometry: Trigonal Bipyramidal
Molecular Geometry: T - Shaped
Linear Shape
Electron Geometry: Trigonal Bipyramidal
Molecular Geometry: Linear
Square Pyramidal Shape
Electron Geometry: Octahedral
Molecular geometry: Square Pyramidal
Square Planar Shape
Electron Geometry: Octahedral
Molecular geometry: Square plane
Trigonal Planar(bent)
electron geometry: trigonal planar
molecular geometry: bent