CD.3 Flashcards

Naming molecules containing benzene rings

1
Q

What are arenes?

A

Arenes are aromatic compounds that contain only C and H, they are often referred to as aromatic hydrocarbons.

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2
Q

Typical arenes are derivatives of which aromatic molecule?

A

Benzene.

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3
Q

A benzene ring in which one of the hydrogen is substitued with another group is known as what group?

A

Phenyl group.

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4
Q

What is an example of a situation when the phenyl suffix is used rather than the benzene suffix to indicate the presence of a benzene ring?

A

When the group attached to the benzene ring contains an alkene group.

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5
Q

Aromatic compounds are typically molecules that contain which group?

A

Benzene.

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6
Q

What property are aromatic compounds generally known to possess?

A

Special stability that result from the delocalisation of electrons in a conjugated system.

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7
Q

What are the three structural feature to look for when deciding if a conjugated system is aromatic?

A
  1. Planar
  2. Cyclic
  3. Possess 4n+2 number of delocalised π electrons (i.e.6,10,14)
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8
Q

Can aromatic systems have rings where one or more atom not being carbon?

A

Yes, nitrogen atoms are typically found in rings of aromatic systems.

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9
Q

What is the relationship between aromatic compounds and arenes?

A

All arenes are aromatic, not all aromatic compounds are arenes.
Therefore we can say that arene is a subgroup of aromatic compounds.

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10
Q

What is the compound called when a hydrogen on the benzene ring is replaced by a chlorine atom?

A

Chlorobenzene

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11
Q

What is a nitro group?

A

-NO2

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12
Q

What is the compound called when a hydrogen on the benzene ring is replaced by a nitro group?

A

Nitrobenzene

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13
Q

What is the compound called when a hydrogen on the benzene ring is replaced by a carboxyl group, -COOH?

A

Benzoic acid

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14
Q

What is a sulfonic acid group?

A

-SO3H, where the sulfur is bonded to an R group, double bonded to two oxygens respectively, and bonded to another OH group.

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15
Q

What is the compound called when a hydrogen on the benzene ring is replaced by a sulfonic acid group?

A

Benzene sulfonic acid

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16
Q

What is the compound called when a hydrogen on the benzene ring is replaced by a hydroxyl group, -OH?

A

Phenol

17
Q

What is the compound called when a hydrogen on the benzene ring is replaced by an amine group, -NH2?

A

Phenylamine

18
Q

When is the phenyl prefix used when naming an ester?

A

When the alcohol group is attached to a benzene ring, so when the alcohol reactant is phenol.

19
Q

When is the benzoate suffix used when naming an ester?

A

When the acid group is attached to a benzene ring, so when the acid reactant is the benzoic acid.