Carbohydrates Flashcards
Classification
- Size of base carbon chain
- Number of sugar units
- Location of C=O
- Stereochemistry
Functions
- Energy Metabolism
- Structural
- Precursors of DNA & RNA
- Cells surface marker
Functions - Energy metabolism
a. Fuel - glucose and its derivates produce energy for immediate use
b. Storage - starch is stored by plants while glycogen is stored by animals in the liver and muscles
Functions - Structural
a. Provides scaffolding for bacterial and plant cell walls
b. Exoskeleton shells for arthropods
c. Lubricative coating to cells
Functions - Precursors of DNA & RNA
a. Serves a chemical structural role
b. Polar sites for the catalytic processes of RNA
Functions - Cell surface marker
a. Immune protection/recognition
b. Cell-cell recognition
c. Host-pathogen interaction
Structure of common carbohydrates
- Chains of C
- Contains an aldehyde or ketone
- Contains a hydroxyl group
Physical characteristics
- Hydrogen bonding with OH groups
- High melting and boiling points
- Soluble in water
- Insoluble in non-polar solvents
- Natural occurring optical isomers are D-sugars
- Most monosaccharides and disaccharides are sweet tasting
- Most monosaccharides are chiral
- Exists in cyclic structure in aqueous solutions
Chemical characteristics
- Have at least 1 or often 2 or more asymmetric centers.
- Able to exist in either linear or ring structures
- Capacity to form polymers via glycosidic bonds
- Potential to form multiple hydrogen bonds with water or other molecules in their environments
Reactions
- Oxidation-Reduction
- Esterification
- Amino derivates
- Glycoside formation