carbohydrates Flashcards
describe monosaccharides-
- most common is glucose
- naturally occurring
- can’t be hydrolyzed into a smaller unit
what is the most commonly found monosaccharide
glucose
when is a monosaccharide considered a reducing sugar
- considered a reducing sugar when the anomeric carbon is free
describe disaccharides
- most common is sucrose
- two monosaccharides joined by an acetyl bond (glycosidic)
what kind of bond joins monosaccharides together, forming polysaccharides?
the monosaccharides are joined by an acetyl bond- aka glycosidic bond
what is the ratio of H:O in all CHO
2:1
position of triode monosaccharides?
metabolism of glucose
position of pentose monosaccharides?
components of DNA and RNA
position of hexose monosaccharides
nutritionally the most important
what is a chiral carbon?
a carbon with four different components attached
what are the two types of chiral carbons?
- enantiomers
- diastereomers
what are enantiomers
mirror images
what are diastereomers
not a mirror image
how do you determine a D vs an L sugar
- determined by the -OH group on the highest chiral carbon
- Oh on the right= D
- OH on the left = L
how do you determine the number of stereoisomers for a molecule?
stereoisomers= 2^n
n= # chiral carbons
are D or L sugars more nutritionally important?
D are nutritionally more important because digestive enzymes are stereospecific for D sugars
what are the basic rules for nomenclature in terms of converting towards fischer projection to Haworth model
LAB vs RBa
(left/above/beta)
(right/below/alpha)
describe sucrose
- found in sugar cane and fruits
- product of glucose + fructose
- non-reducing
describe lactose
- found in milk
- product of galactose + glucose
- reducing
describe maltose
- found in beer and liquor
- glucose + glucose
- reducing
describe polysaccharides
- long strings or branches of monosaccharides (min 6) attached by glycosidic bonds
what is the polysaccharide in plants
starch (amylose, amylopectin)
what is the polysaccharide in animal tissue
glycogen
what is the advantage for branched polysaccharides
this provides a larger number of ends from which to cleave glucose when energy is needed
describe cellulose
- both a dietary fibre and functional fibre (naturally occurring but also added to foods for supplement)
- poorly fermented by human gut bacteria
- rich in bran, legumes, nuts, peas