Carbohydrates Flashcards

1
Q

Epimer

A

2 sugars that differ in the configuration of 1 carbon (type of diasteriomer). Require 2+ chiral centers.

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2
Q

Anomeric carbon

A

Epimer at the hemiacetal/acetal carbon. Also known as reducing end.

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3
Q

Mutarotation

A

Conversion between alpha and beta anomers.

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4
Q

5 membered O containing ring

A

Furan ring.

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5
Q

6 membered O containing ring

A

Pyran ring

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6
Q

Disaccharides

A

Formed by condensation reaction between alcohol groups of two monosaccharides.

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7
Q

Aldehyde + alcohol =`

A

Hemiacetal.

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8
Q

Ketone + alcohol =

A

Hemiketal.

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9
Q

Linkage between two monosaccharides

A

O-glycosidic linkage.

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10
Q

Functions of homopolysaccharides

A

Energy storage and structural function.

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11
Q

Functions of heteropolysaccharides

A

Structural function and cellular function.

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12
Q

What is the main storage polysaccharide in plants?

A

Starch, a mixture of two homopolysaccharides of glucose

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13
Q

Glycogen

A

Main carbohydrate storage system in animal cells, mainly stored in the liver.

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14
Q

Amylopectin

A

Branched homopolysaccharide, glucose is the monomer.

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15
Q

Cellulose

A

Fibrous, water insoluble polymer of unbranched homopolysaccharide of glucose found in the cell wall of plants.

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16
Q

Branched heteropolysaccharides

A

Mono and oligosaccharides added onto proteins.

17
Q

N-linked oligosaccharides

A

Added onto proteins in preassembled oligosaccharide units, added to proteins destined to the extracellular side.

18
Q

O-linked oligosaccharides

A

Added to proteins one monosaccharide at a time, added to proteins that are destined to the intra and extracellular sides.