Carbohydrates 5: Structural Units Flashcards
Properties of cellulose
Found in cell walls Tough Insoluble Fibrous Homo polysaccharide 15 000 b glucose
Structure of cellulose
Straight chain of b glucose
How are the b glucose molecules aligned?
Every other molecule is flipped 180 degrees
What stops the chain spiraling
1-4 glycosidic bond and the 180 degree flip and hydrogen bonding
How are cellulose macro fibrils formed
The b glucose chains form cellulose chains 60 to 70 of them form micro fibrils and 400 microfibrils bundle to form a macro fibrils which criss crosses and overlaps forming the cellulose structure
How is cellulose strengthened
Hydrogen bonds between the cellulose chains
Why is cellulose a great material for cell walls?
Micro/macro fibrils have high tensile strength because of hydrogen and glycosidic bonds
Macro fibrils run in all directions (criss cross)
Difficult to digest because the glycosidic bonds are less easy to break.
What helps the plant cell wall do its job well?
Each cell needs strength to support the plant(no skeletons)
Space between macro fibrils for water and mineral ions to pass through making the cell wall permeable.
The wall has high tensile strength preventing lysis
Macro fibrils can be reinforced making parts waterproof.
What are some example of things which contain cellulose?
Cotton, cellophane, celluloid, paper
What are bacterial cell walls made of?
Peptidoglycan made from long polysaccharide chains cross linked by peptide chains(made of amino acid)
What are exoskeletons made of?
Chitin which has a acetyl amino group rather than a hydroxyl group on carbon 2
It forms cross links of acetylglucosamine
What are macro fibrils imbedded in?
Pectins