Carbohydrates Flashcards
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What are the 2 types of Biochemical substances?
Bioinorganic Substances and Bioorganic Substances
Biochemical substances that DO NOT contain Carbon
Bioinorganic Substances
Biochemical Substances that contains Carbon
Bioorganic Substances
What are the 2 Bioinorganic Substances?
water and inorganic salts
-The most abundant class of bioorganic molecules on planet Earth.
-It constitute about 75% by mass of dry plant materials.
Carbohydrates
What are the 4 Bioorganic substances?
Proteins, Lipids, Carbohydrates, Nucleic Acids
the provides energy reserves for the plants in plants?
starch
it serves as the structural elements in plants?
cellulose
Plants have two main uses for the carbohydrates they produce. What are they?
Starch and Cellulose
What are the 4 classification of carbohydrates?
Monosaccharides, Disaccharides, Oligosaccharides, Polysaccharides
Enumerate 3 MONOSACCHARIDES
Glucose, Fructose, Galactose
Enumerate 3 DISACCHARIDES
Sucrose, Lactose, Maltose
Enumerate 2 OLIGOSACCHARIDES
Trisaccharides, Tetrasaccharides
Enumerate 3 POLYSACCHARIDES
Cellulose, Starch, Glycogen
What are the composition of Sucrose
1 Glucose and 1 Fructose
What are the composition of Lactose
1 Glucose and 1 Galactose
What are the composition of Maltose
2 Glucose
Examples of Trioses
Glyceraldehyde [aldotriose] and Dihydroxyacetone [ketotriose]
Examples of Tetroses
Erythrose [aldotetrose] and Erythulose [ketotetrose]
Examples of Pentoses
Ribose [aldopentose] and
Ribulose [ketopentose]
Examples of Hexoses
Glucose, Galactose, Mannose [aldohexose] and Fructose [ketohexose]
Examples of Heptoses
Sedoheptulose and Mannoheptulose
-are images that coincide at all points when the images are laud upon each other.
Superimposable
-are images where NOT all points coincide when the images are laid upon each
Nonsuperimposable
is an atom in a molecule that has four different groups bonded to it in a tetrahedral orientation.
Chiral Center
the handedness-generating carbon atom.
Chiral Center
is a molecule whose mirror image are superimposable.
Acharial Center
is a molecule whose mirror images are not superimposable.
Chiral Center
How can we identify a Chiral Centel
To have four groups present, all bonds about the chiral center must be single bond.
why is chirality important?
- response of body to the right-handed form of the hormone epinephrine is 20 times greater than its response to the left- handed form.
isomers with a different connectivity
Constitutional Isomers
different compounds with the same molecular formula
Isomers
isomers with the same connectivity but a different orientation of their atoms in space
Stereoisomers
Types of stereoisomers
Enantiomers and Diastereomers
what does “enantios” mean?
Opposite
whose molecules are nonsuperimposable mirror images of each other (L and R handed forms of a molecule with a single chiral center).
Enantiomers
molecules are not mirror images of each other ( contain more than one chiral center).
Diastereomers
German chemist and the developer of the two-dimensional system for specifying chirality
Hermann Emil Fischer
awarded the second Nobel prize in chemistry
Hermann Emil Fischer
British carbohydrate chemist.
Determine the structures of the cyclic forms of glucose
Walter Norman Haworth
In what year was Hermann Emil Fischer awarded the second Nobel prize in chemistry?
1902
Co-recipient of the 1937 Nobel prize in Germany
Walter Norman Haworth
what formula did Walter Norman Haworth develop?
Haworth Projection Formula
MONOSACCHARIDE oxidation can yield/produces three different types of acidic sugars, what are the 3?
Gluconic acid
Glucaric acid
Glucuronic acid
oxidize the aldehyde end of an aldose to give an
ALDONIC ACID
it is a two dimensional structural notation that specifies the three dimensional structure of a cyclic form of a monosaccharide.
Haworth Projection Formula
Oxidize both ends of a monosaccharide at the same time (the carbonyl group and the terminal primary alcohol group)
ALDARIC ACID
oxidize the primary alcohol end of an aldose such as glucose, w/o oxidization of the aldehyde group, to produce an
ALDURONIC