carbohydrates Flashcards

1
Q

Carbohydrates: elements, monomer, function

A

CHO, monosaccharides e.g. glucose, provides energy

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2
Q

what are macromolecules

A

Macro molecules are large complex molecules with a large molecular mass
they are polymers made of similar or different molecules bonded together e.g. lipids

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3
Q

explain Hydrolysis

A

A water molecule is used to hydrolyse the specific chemical bond in the two monomers which produces two separated monomers

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4
Q

Definition of hydrolysis

A

Breakdown with the addition of water

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5
Q

What is Condensation

A

A chemical Bonding between two molecules which produces a water molecule that is lost from the two molecules

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6
Q

what is the glycosidic bond?

A

It is the covalent bond in carbohydrates found between 2 monosaccharides

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7
Q

Examples of monosaccharides (one sugar)
Fruits, vegetables, honey, and nuts

A

Hexose(6 carbons) - glucose (alpha or beta) galactose fructose
Pentose(5 carbons) - deoxyribose ribose

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8
Q

Examples of disaccharides (two sugar molecules linked by glycosidic bond) milk & sugar

A

Sucrose = alpha glucose + fructose
lactose = glactose + inverted beta glucose (1-4 beta glycosidic bond)
Maltose = alpha glucose + alpha glucose

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9
Q

Examples of polysaccharides (many sugar molecules linked) rice, potatoes, corn wheat

A

Starch made of alpha glucose
Glycogen made of alpha glucose
Cellulose made of beta glucose

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10
Q

Starch

A
  • It is an energy storage molecule in plants, excess glucose from photosynthesis is stored as starch.
  • It is relatively big so it’s insoluble in water so it doesn’t interfere with osmotic potential of cells.
  • it contains a lot of chemical bonds which release lots of energy when broken
  • is made up of two polysaccharides Amylose and amylopectin
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11
Q

What is the difference between amylose and amylopectin?

A

Amylose is a long coiled chain forming a helix of alpha glucose linked by 1,4 glycosidic linkage
Amylopectin is a long branched chain of alpha glucose linked by 1,4 glycosidic linkage then 1,6 every 24 units
Combined, they give the appearance of a tightly wound molecule

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12
Q

Glycogen

A
  • Energy storage molecule in mammals and fungi - excess glucose from digestion is stored as glycogen.
  • Insoluble in water so doesn’t interfere with osmotic potential of cells.
  • more branches means it’s compact so energy dense to meet high respiratory demand and other metabolic processes like movement and digestion of large organisms e.g. animals.
  • More branches also means there are more sites where enzymes attach and can hydrolyse the glycosidic bonds to release energy faster
  • Consist of highly branched chains of alpha glucose with 1,4 glycosidic bonds and 1,6 glycosidic bond every 10 units which release lots of energy when broken
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13
Q

How is chitin different to glycogen

A
  • Is the exoskeleton of some insects
  • Contains beta 1,4 glycosidic bonds
  • Contains nitrogen
  • No branching/ 1,6 bonds
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14
Q

Cellulose

A
  • Structural molecule in plant cell wall.
  • Insoluble in water so doesn’t interfere with osmotic potential of cell.
  • Consists of long chains of beta glucose , alternate molecules of beta glucose are inverted (because of the positioning of the OH on carbon 1 (it wouldn’t be adjacent to the OH on carbon 4 of a different molecule)) and bonded by 1-4 glycosidic bonds.
  • Hydrogen bonds occur between separate straight chains of cellulose to form microfibrils that have high tensile strength and allow flexibility
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15
Q

What is the monomer?

A

A small simple molecule which is produced by hydrolysis of a polymer eg monosaccharide/ amino acids / nucleotides

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16
Q

What is polymer?

A

A large chain complex molecule made of similar monomers bonded together and formed by condensation

17
Q

Name the elements present in carbohydrates

A

Carbon hydrogen oxygen
(Cho) is wrong

18
Q

What is the molecular formula of a triose

19
Q

Where is the Pentose sugar ribose found?

A

It is the sugar in RNA

20
Q

Where is the Pentose sugar deoxyribose found

A

It is the sugar in DNA

21
Q

Where is glucose found? what is it used for

A

Throughout the body as a store and it is used for energy during respiration

22
Q

Where is fructose found?

A

fruit and sweet food

23
Q

What is the general formula of a disaccharide?

A

Cn(H2O)n-1

24
Q

When the glycosidic bond is broken, which atoms would need to be replaced in order to produce complete monosaccharides?

25
What does the prefix glyco mean?
Sugar
26
How is fructose different from glucose? Although they are both hexose sugars?
Fructose has a five membered ring structure
27
Name the bonds within a microfibril of cellulose
1,4 beta glycosidic between beta glucose, Hydrogen between two chains
28
What are the properties of cellulose that make it perfect to be a plant cell wall
It’s insoluble Has high tensile strength Is flexible Unreactive
29
Are polysaccharide soluble? Why
They are insoluble Because there are less free OH- groups
30
Name the number of carbon atoms in the disaccharide
12
31
How to test for reducing sugars
Add Benedict Regent to the sample and heat in a water bath at 100° for less than 5 mins, A positive result goes from blue to yellow/red
32
Why is forming long beta glucose chains with hydrogen bonds between the chains useful for cellulose
it allows cellulose molecules to form strong but flexible microfibrils which provide structural support for the cell wall
33
What is the advantage and disadvantage of using amylose as a storage instead of amylopectin
It has a coiled structure so is more compact which allows more of it to be stored in a cell but it has no 1 to 6 bonds so it is broken down slower so the glucose is less readily available
34
what is the physical property of glucose that allows it to be easily transported in the bloodstream
its soluble in water
35
what's the difference between alpha and beta glucose
The OH on the 1st C in beta is On top whereas in Alpha it's below
36
What is the precise bond between the two glucoses to form a Maltose
1,4 alpha glycosidic
37
Rank in an order of most soluble to lease soluble amylose ribose amylopectin glucose
Glucose (most FREE OH- groups) Ribose Amylose Amylopectin (has less free oh- than amylose due to branching)
38
How does the structure of galactose allow it to be a good respiratory substrate?
Bonds in galactose contain energy which can be broken by respiratory enzymes to release energy It is soluble because of the polar OH-groups forming hydrogen bonds with water so it can be transported to where energy is needed