carbohydrates Flashcards
Carbohydrates: elements, monomer, function
CHO, monosaccharides e.g. glucose, provides energy
what are macromolecules
Macro molecules are large complex molecules with a large molecular mass
they are polymers made of similar or different molecules bonded together e.g. lipids
explain Hydrolysis
A water molecule is used to hydrolyse the specific chemical bond in the two monomers which produces two separated monomers
Definition of hydrolysis
Breakdown with the addition of water
What is Condensation
A chemical Bonding between two molecules which produces a water molecule that is lost from the two molecules
what is the glycosidic bond?
It is the covalent bond in carbohydrates found between 2 monosaccharides
Examples of monosaccharides (one sugar)
Fruits, vegetables, honey, and nuts
Hexose(6 carbons) - glucose (alpha or beta) galactose fructose
Pentose(5 carbons) - deoxyribose ribose
Examples of disaccharides (two sugar molecules linked by glycosidic bond) milk & sugar
Sucrose = alpha glucose + fructose
lactose = glactose + inverted beta glucose (1-4 beta glycosidic bond)
Maltose = alpha glucose + alpha glucose
Examples of polysaccharides (many sugar molecules linked) rice, potatoes, corn wheat
Starch made of alpha glucose
Glycogen made of alpha glucose
Cellulose made of beta glucose
Starch
- It is an energy storage molecule in plants, excess glucose from photosynthesis is stored as starch.
- It is relatively big so it’s insoluble in water so it doesn’t interfere with osmotic potential of cells.
- it contains a lot of chemical bonds which release lots of energy when broken
- is made up of two polysaccharides Amylose and amylopectin
What is the difference between amylose and amylopectin?
Amylose is a long coiled chain forming a helix of alpha glucose linked by 1,4 glycosidic linkage
Amylopectin is a long branched chain of alpha glucose linked by 1,4 glycosidic linkage then 1,6 every 24 units
Combined, they give the appearance of a tightly wound molecule
Glycogen
- Energy storage molecule in mammals and fungi - excess glucose from digestion is stored as glycogen.
- Insoluble in water so doesn’t interfere with osmotic potential of cells.
- more branches means it’s compact so energy dense to meet high respiratory demand and other metabolic processes like movement and digestion of large organisms e.g. animals.
- More branches also means there are more sites where enzymes attach and can hydrolyse the glycosidic bonds to release energy faster
- Consist of highly branched chains of alpha glucose with 1,4 glycosidic bonds and 1,6 glycosidic bond every 10 units which release lots of energy when broken
How is chitin different to glycogen
- Is the exoskeleton of some insects
- Contains beta 1,4 glycosidic bonds
- Contains nitrogen
- No branching/ 1,6 bonds
Cellulose
- Structural molecule in plant cell wall.
- Insoluble in water so doesn’t interfere with osmotic potential of cell.
- Consists of long chains of beta glucose , alternate molecules of beta glucose are inverted (because of the positioning of the OH on carbon 1 (it wouldn’t be adjacent to the OH on carbon 4 of a different molecule)) and bonded by 1-4 glycosidic bonds.
- Hydrogen bonds occur between separate straight chains of cellulose to form microfibrils that have high tensile strength and allow flexibility
What is the monomer?
A small simple molecule which is produced by hydrolysis of a polymer eg monosaccharide/ amino acids / nucleotides
What is polymer?
A large chain complex molecule made of similar monomers bonded together and formed by condensation
Name the elements present in carbohydrates
Carbon hydrogen oxygen
(Cho) is wrong
What is the molecular formula of a triose
C3H6O3
Where is the Pentose sugar ribose found?
It is the sugar in RNA
Where is the Pentose sugar deoxyribose found
It is the sugar in DNA
Where is glucose found? what is it used for
Throughout the body as a store and it is used for energy during respiration
Where is fructose found?
fruit and sweet food
What is the general formula of a disaccharide?
Cn(H2O)n-1
When the glycosidic bond is broken, which atoms would need to be replaced in order to produce complete monosaccharides?
O H2